Reversible C–C Bond Scission and C–H Bond Activation in the Butterfly Acetylide Clusters Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe)

Yun Chi; Pei-Chiun Su; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1021/om00012a011

Reversible C–C Bond Scission and C–H Bond Activation in the Butterfly Acetylide Clusters Cp*WOs₃(CO)₁₁(CCR) (R = Ph, Bu, CH₂OMe)

Yun Chi, Pei-Chiun Su, Shie-Ming Peng, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

16 Citations (Scopus)

Abstract

The tetranuclear acetylide compounds Cp*WOs₃(CO)₁₁(CCR) (R = Ph, Bu, CH₂OMe), depending on the substituents of the acetylide ligand, undergo reversible C–C bond scission and C–H activation to afford the carbido–alkylidyne cluster Cp*WOs₃(CO)₁₀(μ₄-C)(μ-CPh) and the carbido–vinylidene clusters Cp*WOs₃(CO)₉(μ₄-C)(μ-H)(μ-CCHR′) (R′ = Pr, OMe), respectively.

Original language	English
Pages (from-to)	5483-5485
Journal	Organometallics
Volume	14
Issue number	12
DOIs	https://doi.org/10.1021/om00012a011
Publication status	Published - 1 Dec 1995
Externally published	Yes

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@article{990bdafd0be5459d81b2e24bebaa8996,

title = "Reversible C–C Bond Scission and C–H Bond Activation in the Butterfly Acetylide Clusters Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe)",

abstract = "The tetranuclear acetylide compounds Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe), depending on the substituents of the acetylide ligand, undergo reversible C–C bond scission and C–H activation to afford the carbido–alkylidyne cluster Cp*WOs3(CO)10(μ4-C)(μ-CPh) and the carbido–vinylidene clusters Cp*WOs3(CO)9(μ4-C)(μ-H)(μ-CCHR′) (R′ = Pr, OMe), respectively.",

author = "Yun Chi and Pei-Chiun Su and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1995",

month = dec,

day = "1",

doi = "10.1021/om00012a011",

language = "English",

volume = "14",

pages = "5483--5485",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Reversible C–C Bond Scission and C–H Bond Activation in the Butterfly Acetylide Clusters Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe)

AU - Chi, Yun

AU - Su, Pei-Chiun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1995/12/1

Y1 - 1995/12/1

N2 - The tetranuclear acetylide compounds Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe), depending on the substituents of the acetylide ligand, undergo reversible C–C bond scission and C–H activation to afford the carbido–alkylidyne cluster Cp*WOs3(CO)10(μ4-C)(μ-CPh) and the carbido–vinylidene clusters Cp*WOs3(CO)9(μ4-C)(μ-H)(μ-CCHR′) (R′ = Pr, OMe), respectively.

AB - The tetranuclear acetylide compounds Cp*WOs3(CO)11(CCR) (R = Ph, Bu, CH2OMe), depending on the substituents of the acetylide ligand, undergo reversible C–C bond scission and C–H activation to afford the carbido–alkylidyne cluster Cp*WOs3(CO)10(μ4-C)(μ-CPh) and the carbido–vinylidene clusters Cp*WOs3(CO)9(μ4-C)(μ-H)(μ-CCHR′) (R′ = Pr, OMe), respectively.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0000839077&origin=recordpage

U2 - 10.1021/om00012a011

DO - 10.1021/om00012a011

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 14

SP - 5483

EP - 5485

JO - Organometallics

JF - Organometallics

IS - 12

ER -