Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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Detail(s)

Original languageEnglish
Pages (from-to)3798-3799
Journal / PublicationOrganometallics
Volume10
Issue number11
Publication statusPublished - 1991
Externally publishedYes

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DOI

DOI
Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-4744368815&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(88221619-938e-424b-b79f-9154c929ded7).html

Abstract

The reversible arm-off dissociation of the tripodal ligand MeC(CH2PPh2)3 in HRh(CO) [η3-MeC-(CH2PPh2)3] (1) under H2/CO (1:1) was studied by high-pressure IR and NMR spectroscopy. The formation of HRh(CO)2 [η2-MeC(CH2PPh2)3] (2) was observed, which explains the low n/i ratio observed for the hydroformylation of olefins. © 1991 American Chemical Society.

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Publication fingerprints text

100
Tripodal Keyphrases
100
Dissociation Keyphrases
100
Hydroformylation Keyphrases
100
dissociation INIS
100
hydroformylation INIS
50
CO 2 Keyphrases
50
High Pressure Keyphrases
50
IR Spectroscopy Keyphrases
50
NMR Spectroscopy Keyphrases
50
Olefins Keyphrases
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Citation Format(s)

[ RIS ] [ BibTeX ]
Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions. / Kiss, Gábor; Horváth, István T.
In: Organometallics, Vol. 10, No. 11, 1991, p. 3798-3799.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review