Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions

Gábor Kiss; István T. Horváth

doi:10.1021/om00057a004

Reversible arm-off dissociation of the tripodal MeC(CH₂PPh₂)₃ in HRh(CO)[MeC(CH₂PPh₂)₃] under hydroformylation conditions

Gábor Kiss, István T. Horváth

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

42 Citations (Scopus)

Abstract

The reversible arm-off dissociation of the tripodal ligand MeC(CH₂PPh₂)₃ in HRh(CO) [η³-MeC-(CH₂PPh₂)₃] (1) under H₂/CO (1:1) was studied by high-pressure IR and NMR spectroscopy. The formation of HRh(CO)₂ [η²-MeC(CH₂PPh₂)₃] (2) was observed, which explains the low n/i ratio observed for the hydroformylation of olefins. © 1991 American Chemical Society.

Original language	English
Pages (from-to)	3798-3799
Journal	Organometallics
Volume	10
Issue number	11
DOIs	https://doi.org/10.1021/om00057a004
Publication status	Published - 1991
Externally published	Yes

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@article{88221619938e424bb79f9154c929ded7,

title = "Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions",

abstract = "The reversible arm-off dissociation of the tripodal ligand MeC(CH2PPh2)3 in HRh(CO) [η3-MeC-(CH2PPh2)3] (1) under H2/CO (1:1) was studied by high-pressure IR and NMR spectroscopy. The formation of HRh(CO)2 [η2-MeC(CH2PPh2)3] (2) was observed, which explains the low n/i ratio observed for the hydroformylation of olefins. {\textcopyright} 1991 American Chemical Society.",

author = "G{\'a}bor Kiss and Horv{\'a}th, {Istv{\'a}n T.}",

year = "1991",

doi = "10.1021/om00057a004",

language = "English",

volume = "10",

pages = "3798--3799",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Reversible arm-off dissociation of the tripodal MeC(CH2PPh2)3 in HRh(CO)[MeC(CH2PPh2)3] under hydroformylation conditions

AU - Kiss, Gábor

AU - Horváth, István T.

PY - 1991

Y1 - 1991

N2 - The reversible arm-off dissociation of the tripodal ligand MeC(CH2PPh2)3 in HRh(CO) [η3-MeC-(CH2PPh2)3] (1) under H2/CO (1:1) was studied by high-pressure IR and NMR spectroscopy. The formation of HRh(CO)2 [η2-MeC(CH2PPh2)3] (2) was observed, which explains the low n/i ratio observed for the hydroformylation of olefins. © 1991 American Chemical Society.

AB - The reversible arm-off dissociation of the tripodal ligand MeC(CH2PPh2)3 in HRh(CO) [η3-MeC-(CH2PPh2)3] (1) under H2/CO (1:1) was studied by high-pressure IR and NMR spectroscopy. The formation of HRh(CO)2 [η2-MeC(CH2PPh2)3] (2) was observed, which explains the low n/i ratio observed for the hydroformylation of olefins. © 1991 American Chemical Society.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-4744368815&origin=recordpage

U2 - 10.1021/om00057a004

DO - 10.1021/om00057a004

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 10

SP - 3798

EP - 3799

JO - Organometallics

JF - Organometallics

IS - 11

ER -