Recognition‐improved monolayer formation on air‐water interface
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 385-390 |
Journal / Publication | Chinese Journal of Chemistry |
Volume | 13 |
Issue number | 5 |
Publication status | Published - Sept 1995 |
Externally published | Yes |
Link(s)
Abstract
Molecular recognition mechanism was introduced into the monolayer formation of two barbituric derivatives, B1 and B2. on a series of melamine derivatives containing water subphase. The recognition pattern was found that each barbituric(or melamine) group forms 3‐fold H‐bonds on its two edges, respectively, with two of its neighboring melamine(barbituric) cores in the ratio of 1:1 on air‐water interface. The area per molecule in this pattern is about 60–65 Å<sup>2</sup> for both B1 and B2. Such recognition improves the monolayer formation of B1 by increasing the collapse pressure around 20 mN/M and modulates the intermolecular distance of B2 in monolayer These effects should be quite meaningful for both theoretical research and practical application of Langmuir‐Blodgett films, especially. Copyright © 1995 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
Research Area(s)
- barbituric acid derivatives, melamine derivatives, molecular recognition, Monolayer
Bibliographic Note
Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].
Citation Format(s)
Recognition‐improved monolayer formation on air‐water interface. / Chai, Xiang‐Dong; Chen, Si‐Guang; Zhou, Yong‐Liang et al.
In: Chinese Journal of Chemistry, Vol. 13, No. 5, 09.1995, p. 385-390.
In: Chinese Journal of Chemistry, Vol. 13, No. 5, 09.1995, p. 385-390.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review