Rechargeable Iodine Batteries: Fundamentals, Advances, and Perspectives

Shuo Yang; Xun Guo; Haiming Lv; Cuiping Han; Ao Chen; Zijie Tang; Xinliang Li; Chunyi Zhi; Hongfei Li

doi:10.1021/acsnano.2c06220

Rechargeable Iodine Batteries: Fundamentals, Advances, and Perspectives

Shuo Yang, Xun Guo, Haiming Lv, Cuiping Han, Ao Chen, Zijie Tang, Xinliang Li, Chunyi Zhi^*, Hongfei Li^*

^*Corresponding author for this work

Department of Materials Science and Engineering

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

74 Citations (Scopus)

Abstract

Lattice distortion and structure collapse are two intrinsic issues of intercalative-type electrodes derived from repeated ion shuttling. In contrast, rechargeable iodine batteries (RIBs) based on the conversion reaction of iodine stand out for high reversibility and satisfying voltage output characteristics no matter when dealing with both monovalent and multivalent ions. Foreseeable performance superiorities lead to an influx of considerable focus and thus a renaissance in RIBs. This review provides a comprehensive overview of the fundamental chemistry of RIBs from the perspectives of physicochemical properties, conversion mechanism, and existing issues. Fur-thermore, we refine the optimization strategies for high-performance RIBs, focusing on physical adsorption and chemical interaction strengthening, electrolytes regulation, and nanoscale-iodine design. Then the pros and cons of tremendous RIBs are compared and specified. Ultimately, we conclude with remaining challenges and perspectives to our best knowledge, which may inspire the construction of next-generation RIBs.

Original language	English
Pages (from-to)	13554–13572
Journal	ACS Nano
Volume	16
Issue number	9
Online published	24 Aug 2022
DOIs	https://doi.org/10.1021/acsnano.2c06220
Publication status	Published - 27 Sept 2022

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Full text of this publication does not contain sufficient affiliation information. With consent from the author(s) concerned, the Research Unit(s) information for this record is based on the existing academic department affiliation of the author(s). Related Research Unit(s) information for this record is supplemented by the author(s) concerned.

Research Keywords

iodine batteries
multivalent ions
conversion mechanism
shuttling effect
physical/chemical interaction
electrolytes regulation
electrochemical performance
energy storage
LITHIUM-IODINE
IONIC LIQUID
ELECTROCHEMICAL OXIDATION
CATHODE MATERIALS
CARBON MATERIALS
NITROGEN
SULFUR
LIFE
ELECTRODE
REDUCTION

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title = "Rechargeable Iodine Batteries: Fundamentals, Advances, and Perspectives",

abstract = "Lattice distortion and structure collapse are two intrinsic issues of intercalative-type electrodes derived from repeated ion shuttling. In contrast, rechargeable iodine batteries (RIBs) based on the conversion reaction of iodine stand out for high reversibility and satisfying voltage output characteristics no matter when dealing with both monovalent and multivalent ions. Foreseeable performance superiorities lead to an influx of considerable focus and thus a renaissance in RIBs. This review provides a comprehensive overview of the fundamental chemistry of RIBs from the perspectives of physicochemical properties, conversion mechanism, and existing issues. Fur-thermore, we refine the optimization strategies for high-performance RIBs, focusing on physical adsorption and chemical interaction strengthening, electrolytes regulation, and nanoscale-iodine design. Then the pros and cons of tremendous RIBs are compared and specified. Ultimately, we conclude with remaining challenges and perspectives to our best knowledge, which may inspire the construction of next-generation RIBs.",

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author = "Shuo Yang and Xun Guo and Haiming Lv and Cuiping Han and Ao Chen and Zijie Tang and Xinliang Li and Chunyi Zhi and Hongfei Li",

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doi = "10.1021/acsnano.2c06220",

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AU - Chen, Ao

AU - Tang, Zijie

AU - Li, Xinliang

AU - Zhi, Chunyi

AU - Li, Hongfei

N1 - Full text of this publication does not contain sufficient affiliation information. With consent from the author(s) concerned, the Research Unit(s) information for this record is based on the existing academic department affiliation of the author(s). Related Research Unit(s) information for this record is supplemented by the author(s) concerned.

PY - 2022/9/27

Y1 - 2022/9/27

N2 - Lattice distortion and structure collapse are two intrinsic issues of intercalative-type electrodes derived from repeated ion shuttling. In contrast, rechargeable iodine batteries (RIBs) based on the conversion reaction of iodine stand out for high reversibility and satisfying voltage output characteristics no matter when dealing with both monovalent and multivalent ions. Foreseeable performance superiorities lead to an influx of considerable focus and thus a renaissance in RIBs. This review provides a comprehensive overview of the fundamental chemistry of RIBs from the perspectives of physicochemical properties, conversion mechanism, and existing issues. Fur-thermore, we refine the optimization strategies for high-performance RIBs, focusing on physical adsorption and chemical interaction strengthening, electrolytes regulation, and nanoscale-iodine design. Then the pros and cons of tremendous RIBs are compared and specified. Ultimately, we conclude with remaining challenges and perspectives to our best knowledge, which may inspire the construction of next-generation RIBs.

AB - Lattice distortion and structure collapse are two intrinsic issues of intercalative-type electrodes derived from repeated ion shuttling. In contrast, rechargeable iodine batteries (RIBs) based on the conversion reaction of iodine stand out for high reversibility and satisfying voltage output characteristics no matter when dealing with both monovalent and multivalent ions. Foreseeable performance superiorities lead to an influx of considerable focus and thus a renaissance in RIBs. This review provides a comprehensive overview of the fundamental chemistry of RIBs from the perspectives of physicochemical properties, conversion mechanism, and existing issues. Fur-thermore, we refine the optimization strategies for high-performance RIBs, focusing on physical adsorption and chemical interaction strengthening, electrolytes regulation, and nanoscale-iodine design. Then the pros and cons of tremendous RIBs are compared and specified. Ultimately, we conclude with remaining challenges and perspectives to our best knowledge, which may inspire the construction of next-generation RIBs.

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KW - energy storage

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KW - ELECTROCHEMICAL OXIDATION

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EP - 13572

JO - ACS Nano

JF - ACS Nano

IS - 9

ER -

Rechargeable Iodine Batteries: Fundamentals, Advances, and Perspectives

Abstract

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Research Keywords

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