Recent progress in pyrazinacenes containing nonbenzenoid rings : synthesis, properties and applications

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)2475-2493
Journal / PublicationJournal of Materials Chemistry C
Volume10
Issue number7
Online published4 Jan 2022
Publication statusPublished - 21 Feb 2022

Abstract

Azaacenes have emerged as a new and important class of organic materials, and their synthesis strategies and applications as organic semiconductors have gained significant progress in recent years. Generally, adopting sterically-shielding substituents such as attaching large silylethynyl groups at selected peripheral positions or extending the pi-conjugation with pyrene units is the common method used to stabilize larger azaacenes. However, another way to stabilize and enlarge azaacenes, as well as to tune their optical and electronic properties by inserting nonbenzenoid rings such as four-membered rings into the skeletons, has also been developed but has received much less attention. Therefore, in this review, we summarize the recent progress in their syntheses, properties, and applications in organic electronics. Moreover, we highlight the effect of nonbenzenoid units in the systems. Finally, we discuss the current challenges and perspectives through comparison with conventional azaacenes.

Research Area(s)

  • MEMORY DEVICE APPLICATION, FUSED N-HETEROACENE, PHYSICAL-PROPERTIES, OPTOELECTRONIC PROPERTIES, BUILDING-BLOCKS, METAL-BINDING, LARGER ACENES, AROMATICITY, DERIVATIVES, AZAACENES