Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

Siu-Chung Chan; Chun-Yuen Wong

doi:10.1016/j.ccr.2019.213082

Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

Siu-Chung Chan, Chun-Yuen Wong^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

15 Citations (Scopus)

Abstract

This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.

Original language	English
Article number	213082
Journal	Coordination Chemistry Reviews
Volume	402
Online published	16 Oct 2019
DOIs	https://doi.org/10.1016/j.ccr.2019.213082
Publication status	Published - 1 Jan 2020

Research Keywords

Benzofuroxan
Dinitrosoarene
Nitrosoarene
Redox non-innocence
Ruthenium

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RGC-funded

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10.1016/j.ccr.2019.213082

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title = "Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence",

abstract = "This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.",

keywords = "Benzofuroxan, Dinitrosoarene, Nitrosoarene, Redox non-innocence, Ruthenium",

author = "Siu-Chung Chan and Chun-Yuen Wong",

year = "2020",

month = jan,

day = "1",

doi = "10.1016/j.ccr.2019.213082",

language = "English",

volume = "402",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

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Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence. / Chan, Siu-Chung; Wong, Chun-Yuen.
In: Coordination Chemistry Reviews, Vol. 402, 213082, 01.01.2020.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Recent developments in ruthenium–nitrosoarene chemistry

T2 - Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

AU - Chan, Siu-Chung

AU - Wong, Chun-Yuen

PY - 2020/1/1

Y1 - 2020/1/1

N2 - This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.

AB - This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.

KW - Benzofuroxan

KW - Dinitrosoarene

KW - Nitrosoarene

KW - Redox non-innocence

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=85073192508&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85073192508&origin=recordpage

U2 - 10.1016/j.ccr.2019.213082

DO - 10.1016/j.ccr.2019.213082

M3 - RGC 21 - Publication in refereed journal

SN - 0010-8545

VL - 402

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

M1 - 213082

ER -

Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

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Recent developments in ruthenium–nitrosoarene chemistry: Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

Abstract

Research Keywords

RGC Funding Information

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