Recent developments in ruthenium–nitrosoarene chemistry : Unconventional synthetic strategies, new ligand designs, and exploration of ligands redox non-innocence

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

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Detail(s)

Original languageEnglish
Article number213082
Journal / PublicationCoordination Chemistry Reviews
Volume402
Online published16 Oct 2019
Publication statusPublished - 1 Jan 2020

Abstract

This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.

Research Area(s)

  • Benzofuroxan, Dinitrosoarene, Nitrosoarene, Redox non-innocence, Ruthenium

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