Realizing Green Phosphorescent Light-Emitting Materials from Rhenium(I) Pyrazolato Diimine Complexes
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 1248-1255 |
Journal / Publication | Inorganic Chemistry |
Volume | 42 |
Issue number | 4 |
Online published | 17 Jan 2003 |
Publication status | Published - 24 Feb 2003 |
Externally published | Yes |
Link(s)
Abstract
Two neutral pyrazolato diimine rhenium(I) carbonyl complexes with formula [Re(CO)3(N-N)(btpz)] where N-N = 2,2′-bipyridine (1) and 1,10-phenanathroline (2), and btpz = 3,5-bis(trifluoromethyl) pyrazolate, were synthesized and characterized by elemental analysis, routine spectroscopic methods, and single-crystal X-ray diffraction study. Ground and excited state properties of these complexes were investigated by steady-state and time-resolved spectroscopies. Complexes 1 and 2 show photoluminescent emission in both solution and solid-state at room temperature, arising from metal to ligand charge-transfer (MLCT) transition with strong overlapping of intraligand π → π* transitions. The long-lived excited state lifetimes of complexes 1 and 2, which are on the order of microseconds, indicate the presence of phosphorescent emission. As these complexes hold the potential to serve as phosphors for organic light-emitting diodes (OLEDs), their electroluminescent performances were evaluated by employing them as dopants of various electron transport layer (ETL) or hole transport layer (HTL) hosts. For complex 1, a green electrophosphorescence emission centered at λmax = 530 nm was observed at low turn-on voltage (∼6 V) with luminous power efficiency of 0.72 Im/W, external quantum efficiency of 0.82%, and luminance of 2300 cd/m2 at a current density of 100 mA/cm2.
Research Area(s)
Citation Format(s)
Realizing Green Phosphorescent Light-Emitting Materials from Rhenium(I) Pyrazolato Diimine Complexes. / Ranjan, Sudhir; Lin, Shen-Yi; Hwang, Kuo-Chu et al.
In: Inorganic Chemistry, Vol. 42, No. 4, 24.02.2003, p. 1248-1255.
In: Inorganic Chemistry, Vol. 42, No. 4, 24.02.2003, p. 1248-1255.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review