Reactivity of a Hexaaryldiboron(6) Dianion as Boryl Radical Anions

Our study unveils a novel approach to accessing boryl radicals through the spontaneous homolytic cleavage of B–B bonds. We synthesized a hexaaryl-substituted diboron(6) dianion, 1, via the reductive B–B coupling of 9-borafluorene. Intriguingly, compound 1 exhibits the ability to undergo homolytic B–B bond cleavage, leading to the formation of boryl radical anions, as confirmed by EPR studies, in the presence of the 2.2.2-cryptand at room temperature. Moreover, it directly reacts with diphenylacetylene, producing an unprecedented 1,6-diborylated allene species, where the phenyl ring is dearomatized. Density functional theory computational studies suggest that homolytic B–B bond cleavage is favored in the reaction path, and the formation of the boryl radical anion is crucial for dearomatization. Additionally, it achieves the dearomative diborylation of anthracene and the activation of elemental sulfur/selenium under mild conditions. The borylation products have been successfully characterized by NMR spectra, HRMS, and X-ray single-crystal diffraction. © 2024 American Chemical Society.