Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

Hui-Xian Yeong; Kai-Chung Lau; Hong-Wei Xi; Kok Hwa Lim; Cheuk-Wai So

doi:10.1021/ic9021382

Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

Hui-Xian Yeong
, Kai-Chung Lau
, Hong-Wei Xi
, Kok Hwa Lim
, Cheuk-Wai So

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

39 Citations (Scopus)

Abstract

The reaction of the disilylene [{PhC(NBu^t)₂}Si] ₂ (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBu^t)₂}SiBr] (2). The result shows that the Si^I-Si^I bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. © 2009 American Chemical Society.

Original language	English
Pages (from-to)	371-373
Journal	Inorganic Chemistry
Volume	49
Issue number	2
DOIs	https://doi.org/10.1021/ic9021382
Publication status	Published - 18 Jan 2010

Access Output

10.1021/ic9021382

Other Access Options

Check CityUHK Library

Permanent Link

Right click to copy link

Cite this

@article{c991ad1ef7c8492c96e5f4e3ba969d93,

title = "Reactivity of a disilylene [\{PhC(NBut)2\}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene",

abstract = "The reaction of the disilylene [\{PhC(NBut)2\}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [\{PhC(NBut)2\}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. {\textcopyright} 2009 American Chemical Society.",

author = "Hui-Xian Yeong and Kai-Chung Lau and Hong-Wei Xi and Lim, \{Kok Hwa\} and Cheuk-Wai So",

year = "2010",

month = jan,

day = "18",

doi = "10.1021/ic9021382",

language = "English",

volume = "49",

pages = "371--373",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine

T2 - Synthesis and characterization of a stable monomeric bromosilylene

AU - Yeong, Hui-Xian

AU - Lau, Kai-Chung

AU - Xi, Hong-Wei

AU - Lim, Kok Hwa

AU - So, Cheuk-Wai

PY - 2010/1/18

Y1 - 2010/1/18

N2 - The reaction of the disilylene [{PhC(NBut)2}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. © 2009 American Chemical Society.

AB - The reaction of the disilylene [{PhC(NBut)2}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. © 2009 American Chemical Society.

UR - https://www.scopus.com/pages/publications/74549140230

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-74549140230&origin=recordpage

U2 - 10.1021/ic9021382

DO - 10.1021/ic9021382

M3 - RGC 21 - Publication in refereed journal

C2 - 20014767

SN - 0020-1669

VL - 49

SP - 371

EP - 373

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

Abstract

Access Output

Other Access Options

Permanent Link

Other Files and Links

Fingerprint

Cite this