Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene

Hui-Xian Yeong; Kai-Chung Lau; Hong-Wei Xi; Kok Hwa Lim; Cheuk-Wai So

doi:10.1021/ic9021382

Author(s)

Hui-Xian Yeong
Kai-Chung Lau
Hong-Wei Xi
Kok Hwa Lim
Cheuk-Wai So

Detail(s)

Original language	English
Pages (from-to)	371-373
Journal / Publication	Inorganic Chemistry
Volume	49
Issue number	2
Publication status	Published - 18 Jan 2010

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DOI	DOI https://doi.org/10.1021/ic9021382 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-74549140230&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(c991ad1e-f7c8-492c-96e5-f4e3ba969d93).html

Abstract

The reaction of the disilylene [{PhC(NBu^t)₂}Si] ₂ (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBu^t)₂}SiBr] (2). The result shows that the Si^I-Si^I bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. © 2009 American Chemical Society.

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Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine : Synthesis and characterization of a stable monomeric bromosilylene. / Yeong, Hui-Xian; Lau, Kai-Chung; Xi, Hong-Wei et al.

In: Inorganic Chemistry, Vol. 49, No. 2, 18.01.2010, p. 371-373.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Yeong, H-X, Lau, K-C, Xi, H-W, Lim, KH & So, C-W 2010, 'Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene', Inorganic Chemistry, vol. 49, no. 2, pp. 371-373. https://doi.org/10.1021/ic9021382

Yeong, H-X., Lau, K-C., Xi, H-W., Lim, K. H., & So, C-W. (2010). Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene. Inorganic Chemistry, 49(2), 371-373. https://doi.org/10.1021/ic9021382

Yeong H-X, Lau K-C, Xi H-W, Lim KH, So C-W. Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine: Synthesis and characterization of a stable monomeric bromosilylene. Inorganic Chemistry. 2010 Jan 18;49(2):371-373. doi: 10.1021/ic9021382

Yeong, Hui-Xian ; Lau, Kai-Chung ; Xi, Hong-Wei et al. / Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine : Synthesis and characterization of a stable monomeric bromosilylene. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 2. pp. 371-373.

Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine : Synthesis and characterization of a stable monomeric bromosilylene

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