Reactivity of a disilylene [{PhC(NBut)2}Si] 2 toward bromine : Synthesis and characterization of a stable monomeric bromosilylene

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Original languageEnglish
Pages (from-to)371-373
Journal / PublicationInorganic Chemistry
Volume49
Issue number2
Publication statusPublished - 18 Jan 2010

Abstract

The reaction of the disilylene [{PhC(NBut)2}Si] 2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI-SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. © 2009 American Chemical Society.

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