Reactions of the Mixed-metal Clusters Prepared from Tungsten Acetylide Complexes; X-Ray Structural Analyses of Two Novel Butterfly Clusters with 60 Valence Electrons

Yun Chi; Hsiu-Fu Hsu; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1039/C39910001019

Author(s)

Yun Chi
Hsiu-Fu Hsu
Shie-Ming Peng
Gene-Hsiang Lee

Detail(s)

Original language	English
Pages (from-to)	1019-1023
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	15
Publication status	Published - 1991
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39910001019 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0025908947&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(254d10fe-b07c-467b-88a1-df9b4d0748e8).html

Abstract

Reaction of WL(CO)₃C≡CPh and Os₃(CO)₁₀(C₂R₂) produced WOs₃L(CO)₉(μ₃-CPh)(CCRCR), L = Cp, R = Tol (p-MeC₆H₄) 1a; L = C₅Me₅, R = Me, 1b; treatment of complexes 1 with ditolylacetylene yielded planar clusters WOs₃L(CO)₈(μ₃-CPh)[C(Tol)C(Tol)CCRCR], L = Cp, R = Tol, 2a; L = C₅Me₅, R = Me, 2b; complex 2b underwent reversible loss of CO to produce an unsaturated cluster WOs₃C₅Me₅(CO)₇(μ₃-CPh)[CMeCMeCC(Tol)C(Tol)] 3b; thermolysis of 3b in refluxing xylene induced the rearrangement of the cluster core, giving another unsaturated complex 4b with identical molecular formula; complexes 1a, 3b and 4b have been examined by X-ray diffraction studies.

Citation Format(s)

[ RIS ] [ BibTeX ]

Reactions of the Mixed-metal Clusters Prepared from Tungsten Acetylide Complexes; X-Ray Structural Analyses of Two Novel Butterfly Clusters with 60 Valence Electrons. / Chi, Yun; Hsu, Hsiu-Fu; Peng, Shie-Ming et al.
In: Journal of the Chemical Society, Chemical Communications, No. 15, 1991, p. 1019-1023.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Chi, Y, Hsu, H-F, Peng, S-M & Lee, G-H 1991, 'Reactions of the Mixed-metal Clusters Prepared from Tungsten Acetylide Complexes; X-Ray Structural Analyses of Two Novel Butterfly Clusters with 60 Valence Electrons', Journal of the Chemical Society, Chemical Communications, no. 15, pp. 1019-1023. https://doi.org/10.1039/C39910001019

Chi, Y., Hsu, H.-F., Peng, S.-M., & Lee, G.-H. (1991). Reactions of the Mixed-metal Clusters Prepared from Tungsten Acetylide Complexes; X-Ray Structural Analyses of Two Novel Butterfly Clusters with 60 Valence Electrons. Journal of the Chemical Society, Chemical Communications, (15), 1019-1023. https://doi.org/10.1039/C39910001019

Chi Y, Hsu HF, Peng SM, Lee GH. Reactions of the Mixed-metal Clusters Prepared from Tungsten Acetylide Complexes; X-Ray Structural Analyses of Two Novel Butterfly Clusters with 60 Valence Electrons. Journal of the Chemical Society, Chemical Communications. 1991;(15):1019-1023. doi: 10.1039/C39910001019

Chi, Yun ; Hsu, Hsiu-Fu ; Peng, Shie-Ming et al. / Reactions of the Mixed-metal Clusters Prepared from Tungsten Acetylide Complexes; X-Ray Structural Analyses of Two Novel Butterfly Clusters with 60 Valence Electrons. In: Journal of the Chemical Society, Chemical Communications. 1991 ; No. 15. pp. 1019-1023.