Rational designs and engineering of hollow micro-/nanostructures as sulfur hosts for advanced lithium-sulfur batteries

Zhen Li, Hao Bin Wu, Xiong Wen Lou*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

621 Citations (Scopus)
23 Downloads (CityUHK Scholars)

Abstract

Lithium-sulfur (Li-S) batteries have attracted much attention in the field of electrochemical energy storage and conversion. As a vital part of the cathode electrode, the host materials of sulfur usually have a strong impact on the capacity, energy density, cycle life and Coulombic efficiency of Li-S batteries. With their unique physical and chemical properties, the rationally designed hollow nanostructures show conspicuous advantages as sulfur hosts, and have significantly improved the overall performance of Li-S cells. The scope of this review considers the unique structural advantages of hollow host materials for high-performance Li-S batteries, together with a summary of recent advances in the design and synthesis of various hollow micro-/nanostructures with controlled shapes, tailored shell structures and designed chemical compositions. Finally, we propose some emerging requirements of sulfur hosts which we hope will shed some light on the future development trend of hollow structures for advanced Li-S batteries. © 2016 The Royal Society of Chemistry.
Original languageEnglish
Pages (from-to)3061-3070
JournalEnergy and Environmental Science
Volume9
Issue number10
DOIs
Publication statusPublished - 1 Oct 2016
Externally publishedYes

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