Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex

Wai-Lun Man; William W. Y. Lam; Hoi-Ki Kwong; Shek-Man Yiu; Tai-Chu Lau

doi:10.1002/anie.201204136

Author(s)

Wai-Lun Man
William W. Y. Lam
Hoi-Ki Kwong
Shek-Man Yiu
Tai-Chu Lau

Detail(s)

Original language	English
Pages (from-to)	9101-9104
Journal / Publication	Angewandte Chemie - International Edition
Volume	51
Issue number	36
Publication status	Published - 3 Sept 2012

Link(s)

DOI	DOI https://doi.org/10.1002/anie.201204136 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-84865852151&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(b32fb34c-d65d-42fe-beb2-2c6ed52a7e56).html

Abstract

Kinetic and mechanistic studies on the intermolecular activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI) nitride were performed. The initial, rate-limiting step, the hydrogen atom transfer (HAT) from the alkane to Ru ^VI≡N, generates Ru ^V=NH and RC ^.HCH ₂R. The following steps involve N-rebound and desaturation. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Research Area(s)

alkanes, C-H activation, desaturation, hydrogen transfer, nitride complexes

Citation Format(s)

[ RIS ] [ BibTeX ]

Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex. / Man, Wai-Lun; Lam, William W. Y.; Kwong, Hoi-Ki et al.
In: Angewandte Chemie - International Edition, Vol. 51, No. 36, 03.09.2012, p. 9101-9104.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Man, W-L, Lam, WWY, Kwong, H-K, Yiu, S-M & Lau, T-C 2012, 'Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex', Angewandte Chemie - International Edition, vol. 51, no. 36, pp. 9101-9104. https://doi.org/10.1002/anie.201204136

Man, W-L., Lam, W. W. Y., Kwong, H-K., Yiu, S-M., & Lau, T-C. (2012). Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex. Angewandte Chemie - International Edition, 51(36), 9101-9104. https://doi.org/10.1002/anie.201204136

Man W-L, Lam WWY, Kwong H-K, Yiu S-M, Lau T-C. Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex. Angewandte Chemie - International Edition. 2012 Sept 3;51(36):9101-9104. doi: 10.1002/anie.201204136

Man, Wai-Lun ; Lam, William W. Y. ; Kwong, Hoi-Ki et al. / Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 36. pp. 9101-9104.