Multilevel molecular electronic species: Electrochemical reduction of a [2 x 2] Co4/(II) grid-type complex by 11 electrons in 10 reversible steps

Mario Ruben; Esther Breuning; Jean-Paul Gisselbrecht; Jean-Marie Lehn

doi:10.1002/1521-3773(20001117)39:22<4139::AID-ANIE4139>3.0.CO;2-Y

Author(s)

Mario Ruben
Esther Breuning
Jean-Paul Gisselbrecht
Jean-Marie Lehn

Detail(s)

Original language	English
Pages (from-to)	4139-4142
Journal / Publication	Angewandte Chemie - International Edition
Volume	39
Issue number	22
Publication status	Published - 17 Nov 2000
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/1521-3773(20001117)39:22<4139::AID-ANIE4139>3.0.CO;2-Y Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0034680651&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(973ccf47-67a1-4d98-9b6d-1b6215bc1ac4).html

Abstract

The highest number, so far, of well-resolved, completely reversible reduction waves of a molecular compound is found during the stepwise reduction of the tetranuclear [2 x 2] Co₄/(II) grid-type complex 1 (R = Ph) by a total of 11 electrons. The associated (differential) cyclic voltammogram (see picture) shows ten reduction waves, which represent ten reduced species of remarkable stability.

Research Area(s)

Cobalt, Cyclic voltammetry, Electrochemistry, N ligands, Supramolecular chemistry, Tetranuclear complexes

Bibliographic Note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to lbscholars@cityu.edu.hk.

Citation Format(s)

[ RIS ] [ BibTeX ]

Multilevel molecular electronic species : Electrochemical reduction of a [2 x 2] Co₄/(II) grid-type complex by 11 electrons in 10 reversible steps. / Ruben, Mario; Breuning, Esther; Gisselbrecht, Jean-Paul et al.

In: Angewandte Chemie - International Edition, Vol. 39, No. 22, 17.11.2000, p. 4139-4142.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Ruben, M, Breuning, E, Gisselbrecht, J-P & Lehn, J-M 2000, 'Multilevel molecular electronic species: Electrochemical reduction of a [2 x 2] Co₄/(II) grid-type complex by 11 electrons in 10 reversible steps', Angewandte Chemie - International Edition, vol. 39, no. 22, pp. 4139-4142. https://doi.org/10.1002/1521-3773(20001117)39:22<4139::AID-ANIE4139>3.0.CO;2-Y

Ruben, M., Breuning, E., Gisselbrecht, J-P., & Lehn, J-M. (2000). Multilevel molecular electronic species: Electrochemical reduction of a [2 x 2] Co₄/(II) grid-type complex by 11 electrons in 10 reversible steps. Angewandte Chemie - International Edition, 39(22), 4139-4142. https://doi.org/10.1002/1521-3773(20001117)39:22<4139::AID-ANIE4139>3.0.CO;2-Y

Ruben M, Breuning E, Gisselbrecht J-P, Lehn J-M. Multilevel molecular electronic species: Electrochemical reduction of a [2 x 2] Co₄/(II) grid-type complex by 11 electrons in 10 reversible steps. Angewandte Chemie - International Edition. 2000 Nov 17;39(22):4139-4142. doi: 10.1002/1521-3773(20001117)39:22<4139::AID-ANIE4139>3.0.CO;2-Y

Ruben, Mario ; Breuning, Esther ; Gisselbrecht, Jean-Paul et al. / Multilevel molecular electronic species : Electrochemical reduction of a [2 x 2] Co₄/(II) grid-type complex by 11 electrons in 10 reversible steps. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 22. pp. 4139-4142.

Multilevel molecular electronic species : Electrochemical reduction of a [2 x 2] Co4/(II) grid-type complex by 11 electrons in 10 reversible steps