Topologically diverse shape-persistent bis-(Zn-salphen) catalysts : efficient cyclic carbonate formation under mild conditions
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 1017-1020 |
| Journal / Publication | Chemical Communications |
| Volume | 52 |
| Issue number | 5 |
| Online published | 12 Nov 2015 |
| Publication status | Published - 18 Jan 2016 |
Link(s)
Abstract
By adopting a shape-persistent bimetallic design approach, high initial molecular turnover frequencies (up to 14 800 h-1) for coupling of CO2 with epoxides in conjunction with nBu4NI, plus excellent yields under mild conditions (1 bar of CO2, 45°C) have been achieved for catalysts containing cofacial Zn-salphen units.
Citation Format(s)
Topologically diverse shape-persistent bis-(Zn-salphen) catalysts : efficient cyclic carbonate formation under mild conditions. / He, Shixiong; Wang, Fuli; Tong, Wah-Leung et al.
In: Chemical Communications, Vol. 52, No. 5, 18.01.2016, p. 1017-1020.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
