[{Pt(CN)(C10H21N4)}6] : A luminescent hexanuclear platinum(II) macrocycle containing chelating dicarbene and bridging cyanide ligands
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 182-184 |
| Journal / Publication | Angewandte Chemie - International Edition in English |
| Volume | 37 |
| Issue number | 1-2 |
| Publication status | Published - 1998 |
| Externally published | Yes |
Link(s)
Abstract
A metal →*(carbene) charge-transfer emission was observed for the first time in solution at room temperature for the title compound. This novel hexanuclear platinum macrocycle is formed by self-assembly of six dicarbeneplatinum(II) moieties and six cyanide ligands. The Pt centers occupy six corners of a cube, and the cyanide ligands constitute the edges (depicted schematically on the right; circles = [Pt(C10H21N4)], rectangles = CN).
Research Area(s)
- Carbene complexes, Luminescence, Macrocycles, Platinum, Self-assembly
Citation Format(s)
[{Pt(CN)(C10H21N4)}6] : A luminescent hexanuclear platinum(II) macrocycle containing chelating dicarbene and bridging cyanide ligands. / Lai, S. W.; Cheung, K. K.; Chan, M. C W et al.
In: Angewandte Chemie - International Edition in English, Vol. 37, No. 1-2, 1998, p. 182-184.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
