Direct Electrochemical Reduction of Single-Layer Graphene Oxide and Subsequent Functionalization with Glucose Oxidase

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Original languageEnglish
Pages (from-to)14071-14075
Journal / PublicationJournal of Physical Chemistry C
Volume113
Issue number32
Online published17 Jul 2009
Publication statusPublished - 13 Aug 2009
Externally publishedYes

Abstract

A direct electrochemical method to reduce single-layer graphene oxide (GO) adsorbed on the 3-aminopropyltriethoxysilane (APTES)-modified conductive electrodes is proposed. The reduced GO adsorbed on glassy carbon electrode was modified with glucose oxidase (GOx) by covalent bonding via a polymer generated by electrografting N-succinimidyl acrylate (NSA). The direct electron transfer between the electrode and GOx molecules was realized. The bioactivity of GOx maintains very well on the electrode. The thus-prepared GOx-modified electrode was successfully used to detect glucose. © 2009 American Chemical Society.

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