Interdiffusion in copper-aluminum thin film bilayers. I. Structure and kinetics of sequential compound formation
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 6923-6928 |
Journal / Publication | Journal of Applied Physics |
Volume | 54 |
Issue number | 12 |
Publication status | Published - 1983 |
Externally published | Yes |
Link(s)
Abstract
Interdiffusion in Cu-Al thin film bilayers at temperatures between 160 and 300 °C has been studied by a combination of glancing-incidence x-ray diffraction, Rutherford backscattering spectroscopy, and transmission electron diffraction and microscopy. A sequential intermetallic compound formation was observed in samples with an excess amount of Cu with θ-CuAl2 forming first, followed by η2-CuAl, and γ2- Cu9Al4. In samples with excess Al, the θ-CuAl 2 is the first and the last phase formed. The thickening of these compounds was found to obey a parabolic relationship with time, and especially the thickening of θ-CuAl2 can be described by a prefactor of 7.4 cm2/s and an activation energy of 1.31 eV.
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Citation Format(s)
Interdiffusion in copper-aluminum thin film bilayers. I. Structure and kinetics of sequential compound formation. / Hentzell, H. T.G.; Thompson, R. D.; Tu, K. N.
In: Journal of Applied Physics, Vol. 54, No. 12, 1983, p. 6923-6928.
In: Journal of Applied Physics, Vol. 54, No. 12, 1983, p. 6923-6928.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review