Preparation and Properties of (BEDT-TTF)2Br3H2O Salt

Q.C. Zhang; P.J. Wu; K.J. Jiang; R.S. Ding; Y.Q. Wang; D.B. Zhu

Preparation and Properties of (BEDT-TTF)₂Br3H₂O Salt

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Overview

1 Scopus Citations

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Author(s)

P.J. Wu
K.J. Jiang
R.S. Ding
Y.Q. Wang
D.B. Zhu

Detail(s)

Original language	English
Pages (from-to)	179-182
Journal / Publication	Chinese Chemical Letters
Volume	10
Issue number	2
Publication status	Published - Feb 1999
Externally published	Yes

Link(s)

	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0033421941&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(35cbb579-5c81-48e0-84a6-f020b2747950).html

Abstract

Electrochemical oxidation of BEDT-TTF (bis (ethylenedithio) tetrathiafulvalene) in chloroform/carbon disulfide (3:1) in the presence of Bu₄NBr as a supporting electrolyte at low current density results in the (BEDT-TTF)₂Br3H₂O crystal. Its composition has been established by chemical analysis (Br, C, H, S), XPS and IR. The temperature dependence of the resistance has been studied down to 26K at ambient pressure. This material has weakly metallic behavior above 230K, and becomes a semiconductor below this temperature. The structure of the complex is also described.

Research Area(s)

Charge transfer complex, Electrical properties, Organic conductor, Preparation, Structure

Bibliographic Note

Publication information for this record has been verified with the author(s) concerned.

Citation Format(s)

[ RIS ] [ BibTeX ]

Preparation and Properties of (BEDT-TTF)₂Br3H₂O Salt. / Zhang, Q.C.; Wu, P.J.; Jiang, K.J. et al.

In: Chinese Chemical Letters, Vol. 10, No. 2, 02.1999, p. 179-182.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Zhang, QC, Wu, PJ, Jiang, KJ, Ding, RS, Wang, YQ & Zhu, DB 1999, 'Preparation and Properties of (BEDT-TTF)₂Br3H₂O Salt', Chinese Chemical Letters, vol. 10, no. 2, pp. 179-182.

Zhang, Q. C., Wu, P. J., Jiang, K. J., Ding, R. S., Wang, Y. Q., & Zhu, D. B. (1999). Preparation and Properties of (BEDT-TTF)₂Br3H₂O Salt. Chinese Chemical Letters, 10(2), 179-182.

Zhang QC, Wu PJ, Jiang KJ, Ding RS, Wang YQ, Zhu DB. Preparation and Properties of (BEDT-TTF)₂Br3H₂O Salt. Chinese Chemical Letters. 1999 Feb;10(2):179-182.

Zhang, Q.C. ; Wu, P.J. ; Jiang, K.J. et al. / Preparation and Properties of (BEDT-TTF)₂Br3H₂O Salt. In: Chinese Chemical Letters. 1999 ; Vol. 10, No. 2. pp. 179-182.