Synthesis and X-ray crystal structure of Re4(NBut)8(μ-O)2(μ3-O)2(OSO2CF3)4
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 2647-2650 |
| Journal / Publication | Polyhedron |
| Volume | 10 |
| Issue number | 22 |
| Publication status | Published - 1991 |
| Externally published | Yes |
Link(s)
Abstract
Interaction of Re(NBut)3(NHBut) and CF3SO3H in Et2O leads to the known [Re(NBut)3(NH2But)]O3SCF3 but also to a low yield, presumably via a competitive reaction, of a red compound, Re4(NBut)8(μ-O)2(μ3-O)2(OSO2CF3)4, whose X-ray crystal structure has been determined.
The structure has a Re4O4 core comprising oxo-bridged, five- and six-coordinate rhenium centres. The six-coordinate rhenium centres have cis oriented oxo, NBut and η1-O3SCF3 ligands; the five-coordinate centres have pairs of NBut and μ3-O ligands and a μ-O ligand. © 1991.
The structure has a Re4O4 core comprising oxo-bridged, five- and six-coordinate rhenium centres. The six-coordinate rhenium centres have cis oriented oxo, NBut and η1-O3SCF3 ligands; the five-coordinate centres have pairs of NBut and μ3-O ligands and a μ-O ligand. © 1991.
Citation Format(s)
Synthesis and X-ray crystal structure of Re4(NBut)8(μ-O)2(μ3-O)2(OSO2CF3)4. / Lam, Hon-Wah; Wilkinson, Geoffrey; Williams, David J.
In: Polyhedron, Vol. 10, No. 22, 1991, p. 2647-2650.
In: Polyhedron, Vol. 10, No. 22, 1991, p. 2647-2650.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
