Pt nanoparticles decorated heterostructured g-C₃N₄/Bi₂MoO₆ microplates with highly enhanced photocatalytic activities under visible light

Exploring an efficient and photostable heterostructured photocatalyst is a pivotal scientific topic for worldwide energy and environmental concerns. Herein, we reported that Pt decorated g-C₃N₄/Bi₂MoO₆ heterostructured composites with enhanced photocatalytic performance under visible light were simply synthesized by one-step hydrothermal method for methylene blue (MB) dye degradation. Results revealed that the synthetic Pt decorated g-C₃N₄/Bi₂MoO₆ composites with Bi₂MoO₆ contents of 20 wt.% (Pt@CN/20%BMO) presented the highest photocatalytic activity, exhibiting 7 and 18 times higher reactivity than the pure g-C₃N₄ and Bi₂MoO₆, respectively. Structural analyses showed that Bi₂MoO₆ microplates were anchored on the wrinkled flower-like g-C₃N₄ matrix with Pt decoration, leading to a large expansion of specific surface area from 10.79 m²/g for pure Bi₂MoO₆ to 46.09 m²/g for Pt@CN/20%BMO. In addition, the Pt@CN/20%BMO composites exhibited an improved absorption ability in the visible light region, presenting a promoted photocatalytic MB degradation. Quenching experiments were also conducted to provide solid evidences for the production of hydroxyl radicals (^•OH), electrons (e⁻), holes (h⁺) and superoxide radicals (^•O²⁻) during dye degradation. The findings in this critical work provide insights into the synthesis of heterostructured photocatalysts with the optimization of band gaps, light response and photocatalytic performance in wastewater remediation.