Protonic modulation of redox properties in ionisable [2 x 2] grid-like metalloarrays

Lindsay H. Uppadine; Jean-Paul Gisselbrecht; Jean-Marie Lehn

doi:10.1039/b315352e

Protonic modulation of redox properties in ionisable [2 x 2] grid-like metalloarrays

Lindsay H. Uppadine
, Jean-Paul Gisselbrecht
, Jean-Marie Lehn^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

63 Citations (Scopus)

Abstract

The oxidation state of the cobalt centres can be controlled by modification of the protonation state in [2 x 2] grid-like arrays based on ionisable bis(hydrazone) ligands, allowing conversion of the paramagnetic Co^II₄ into the diamagnetic Co^III₄ grid.

Original language	English
Pages (from-to)	718-719
Journal	Chemical Communications
Volume	10
Issue number	6
Online published	12 Feb 2004
DOIs	https://doi.org/10.1039/b315352e
Publication status	Published - 2004
Externally published	Yes

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@article{3f041d65a89e4b249eac66e29488cfa3,

title = "Protonic modulation of redox properties in ionisable [2 x 2] grid-like metalloarrays",

abstract = "The oxidation state of the cobalt centres can be controlled by modification of the protonation state in [2 x 2] grid-like arrays based on ionisable bis(hydrazone) ligands, allowing conversion of the paramagnetic CoII4 into the diamagnetic CoIII4 grid.",

author = "Uppadine, \{Lindsay H.\} and Jean-Paul Gisselbrecht and Jean-Marie Lehn",

year = "2004",

doi = "10.1039/b315352e",

language = "English",

volume = "10",

pages = "718--719",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Protonic modulation of redox properties in ionisable [2 x 2] grid-like metalloarrays

AU - Uppadine, Lindsay H.

AU - Gisselbrecht, Jean-Paul

AU - Lehn, Jean-Marie

PY - 2004

Y1 - 2004

N2 - The oxidation state of the cobalt centres can be controlled by modification of the protonation state in [2 x 2] grid-like arrays based on ionisable bis(hydrazone) ligands, allowing conversion of the paramagnetic CoII4 into the diamagnetic CoIII4 grid.

AB - The oxidation state of the cobalt centres can be controlled by modification of the protonation state in [2 x 2] grid-like arrays based on ionisable bis(hydrazone) ligands, allowing conversion of the paramagnetic CoII4 into the diamagnetic CoIII4 grid.

UR - https://www.scopus.com/pages/publications/1842431569

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-1842431569&origin=recordpage

U2 - 10.1039/b315352e

DO - 10.1039/b315352e

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 10

SP - 718

EP - 719

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Protonic modulation of redox properties in ionisable [2 x 2] grid-like metalloarrays

Abstract

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