Programmable assemblies of photothermal anisotropic micromotors for multimodal motion

Light-driven micromotors with multiple motion modes offer significantly greater application potential than single-mode micromotors. However, achieving such versatility often requires complex structural designs and precise light focusing on specific micromotor regions, presenting challenges for dynamic operations and microscale precisions. This study introduces programmable assemblies of anisotropic micromotors driven by the photothermal Marangoni effect, produced in bulk via microfluidic technology. Under full-area near-infrared (NIR) irradiation, the micromotor exhibits multiple motion modes, including translation and revolution, while micromotor assemblies display additional rotational motion. Self-assembly of these micromotors is highly controllable and programmable, enabling easy customization of assembled structures to achieve desired motion modes. These features are expected to advance the development of various intelligent self-propelling systems, using multimodal individual micromotors as foundational building blocks. © The Royal Society of Chemistry 2025.