Preparation and Structure of Cp*2Ru2(μ-Cl)(μ-X) (C60), X = H and Cl. Novel Dinuclear Fullerene Complexes with and without Direct Ruthenium-Ruthenium Bonding

Ipe J. Mavunkal; Yun Chi; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1021/om00010a005

Preparation and Structure of Cp*₂Ru₂(μ-Cl)(μ-X) (C₆₀), X = H and Cl. Novel Dinuclear Fullerene Complexes with and without Direct Ruthenium-Ruthenium Bonding

Ipe J. Mavunkal
, Yun Chi
, Shie-Ming Peng
, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

67 Citations (Scopus)

Abstract

Treatment of C₆₀ with stoichiometric amounts of both [Cp*Ru(μ-H)₂]₂ and [Cp*RuCl₂]₂ produced Cp*₂-Ru₂(μ-H)(μ-Cl)(C₆₀) (2), which contains a Ru₂ fragment bound to two conjugated C—C π-bonds. The related C₆₀ derivative Cp*₂Ru₂(μ-Cl₂)(C₆₀) (3) was obtained by using 2 equiv of [Cp*RuCl₂]₂. Formation of a transient cationic species [Cp*RuC₆₀]⁺ is suggested on the basis of FAB mass analysis of 2 and 3.

Original language	English
Pages (from-to)	4454-4456
Journal	Organometallics
Volume	14
Issue number	10
DOIs	https://doi.org/10.1021/om00010a005
Publication status	Published - Oct 1995
Externally published	Yes

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@article{fdf997e93945494baf19301fac0fb3ee,

title = "Preparation and Structure of Cp*2Ru2(μ-Cl)(μ-X) (C60), X = H and Cl. Novel Dinuclear Fullerene Complexes with and without Direct Ruthenium-Ruthenium Bonding",

abstract = "Treatment of C60 with stoichiometric amounts of both [Cp*Ru(μ-H)2]2 and [Cp*RuCl2]2 produced Cp*2-Ru2(μ-H)(μ-Cl)(C60) (2), which contains a Ru2 fragment bound to two conjugated C—C π-bonds. The related C60 derivative Cp*2Ru2(μ-Cl2)(C60) (3) was obtained by using 2 equiv of [Cp*RuCl2]2. Formation of a transient cationic species [Cp*RuC60]+ is suggested on the basis of FAB mass analysis of 2 and 3. ",

author = "Mavunkal, \{Ipe J.\} and Yun Chi and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1995",

month = oct,

doi = "10.1021/om00010a005",

language = "English",

volume = "14",

pages = "4454--4456",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

Preparation and Structure of Cp*₂Ru₂(μ-Cl)(μ-X) (C₆₀), X = H and Cl. Novel Dinuclear Fullerene Complexes with and without Direct Ruthenium-Ruthenium Bonding. / Mavunkal, Ipe J.; Chi, Yun; Peng, Shie-Ming et al.
In: Organometallics, Vol. 14, No. 10, 10.1995, p. 4454-4456.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Preparation and Structure of Cp*2Ru2(μ-Cl)(μ-X) (C60), X = H and Cl. Novel Dinuclear Fullerene Complexes with and without Direct Ruthenium-Ruthenium Bonding

AU - Mavunkal, Ipe J.

AU - Chi, Yun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1995/10

Y1 - 1995/10

N2 - Treatment of C60 with stoichiometric amounts of both [Cp*Ru(μ-H)2]2 and [Cp*RuCl2]2 produced Cp*2-Ru2(μ-H)(μ-Cl)(C60) (2), which contains a Ru2 fragment bound to two conjugated C—C π-bonds. The related C60 derivative Cp*2Ru2(μ-Cl2)(C60) (3) was obtained by using 2 equiv of [Cp*RuCl2]2. Formation of a transient cationic species [Cp*RuC60]+ is suggested on the basis of FAB mass analysis of 2 and 3.

AB - Treatment of C60 with stoichiometric amounts of both [Cp*Ru(μ-H)2]2 and [Cp*RuCl2]2 produced Cp*2-Ru2(μ-H)(μ-Cl)(C60) (2), which contains a Ru2 fragment bound to two conjugated C—C π-bonds. The related C60 derivative Cp*2Ru2(μ-Cl2)(C60) (3) was obtained by using 2 equiv of [Cp*RuCl2]2. Formation of a transient cationic species [Cp*RuC60]+ is suggested on the basis of FAB mass analysis of 2 and 3.

UR - https://www.scopus.com/pages/publications/0000297427

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U2 - 10.1021/om00010a005

DO - 10.1021/om00010a005

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 14

SP - 4454

EP - 4456

JO - Organometallics

JF - Organometallics

IS - 10

ER -