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Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine–dioxime catalysts under both aqueous and organic conditions

  • Chun-Leung Kwok
  • , Shun-Cheung Cheng
  • , Pui-Yu Ho
  • , Shek-Man Yiu
  • , Wai-Lun Man
  • , Vonika Ka-Man Au
  • , Po-Keung Tsang
  • , Chi-Fai Leung*
  • , Chi-Chiu Ko
  • , Marc Robert
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino–dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.
Original languageEnglish
Pages (from-to)7491-7494
Number of pages4
JournalChemical Communications
Volume56
Issue number54
Online published27 May 2020
DOIs
Publication statusPublished - 11 Jul 2020

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