TY - JOUR
T1 - Polarized phosphorescent organic light-emitting devices adopting mesogenic host-guest systems
AU - Liu, Su-Hao
AU - Lin, Ming-Shiang
AU - Chen, Li-Yin
AU - Hong, Yun-Hua
AU - Tsai, Chih-Hung
AU - Wu, Chung-Chih
AU - Poloek, Anurach
AU - Chi, Yun
AU - Chen, Chien-An
AU - Chen, Shaw H.
AU - Hsu, Hsiu-Fu
PY - 2011/1
Y1 - 2011/1
N2 - We report successful realization of workable polarized phosphorescent organic light-emitting devices (OLEDs) by combining a recently developed mesogenic phosphorescent Pt(II) complex and a mesogenic oligofluorene host to form the corresponding mesogenic host-guest emitting system. In the host-guest film, the mesogenic Pt(II) complex tends to aggregate and self-assemble into the columnar stacking arrangement, exhibiting metal-metal-to-ligand charge transfer (MMLCT) emission of the Pt(II) complex. Both the host molecules and guest aggregates in the host-guest films were successfully aligned by using the rubbed conducting polymer as the alignment layer. With such aligned host-guest films, polarized red-emitting OLEDs were successfully implemented, showing an EL polarization ratio of ∼2, a maximal brightness exceeding 2000 cd/m 2, and a cd/A efficiency up to 2.4 cd/A. Due to the particular alignment mechanism of guest aggregates and the unique MMLCT emission mechanism, the polarized OLED exhibiting stronger electroluminescence perpendicular to the rubbing direction than along the rubbing direction.
AB - We report successful realization of workable polarized phosphorescent organic light-emitting devices (OLEDs) by combining a recently developed mesogenic phosphorescent Pt(II) complex and a mesogenic oligofluorene host to form the corresponding mesogenic host-guest emitting system. In the host-guest film, the mesogenic Pt(II) complex tends to aggregate and self-assemble into the columnar stacking arrangement, exhibiting metal-metal-to-ligand charge transfer (MMLCT) emission of the Pt(II) complex. Both the host molecules and guest aggregates in the host-guest films were successfully aligned by using the rubbed conducting polymer as the alignment layer. With such aligned host-guest films, polarized red-emitting OLEDs were successfully implemented, showing an EL polarization ratio of ∼2, a maximal brightness exceeding 2000 cd/m 2, and a cd/A efficiency up to 2.4 cd/A. Due to the particular alignment mechanism of guest aggregates and the unique MMLCT emission mechanism, the polarized OLED exhibiting stronger electroluminescence perpendicular to the rubbing direction than along the rubbing direction.
KW - Liquid crystal
KW - OLEDs
KW - Phosphorescence
KW - Polarized emission
UR - http://www.scopus.com/inward/record.url?scp=78149240663&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-78149240663&origin=recordpage
U2 - 10.1016/j.orgel.2010.09.020
DO - 10.1016/j.orgel.2010.09.020
M3 - RGC 21 - Publication in refereed journal
SN - 1566-1199
VL - 12
SP - 15
EP - 21
JO - Organic Electronics: physics, materials, applications
JF - Organic Electronics: physics, materials, applications
IS - 1
ER -