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Plasma-nitrided high-k polycrystalline nano-array induced by electron irradiation

A. P. Huang, L. Wang, J. B. Xu, Paul K. Chu

    Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

    Abstract

    The microstructure of plasma-nitrided high-k ZrO2 thin films is found to continuously transform and larger size nano-crystals are formed during electron bombardment. Real-time high-resolution transmission electron microscopy (HRTEM) studies show that the plasma-nitrided nano-size particles can self-crystallize and regrow, whereas this phenomenon is not observed in amorphous ZrO2 without N incorporation. Similar results are observed in plasma-nitrided HfO2 samples and fine-scale polycrystalline nano-arrays are obtained by electron irradiation. Our results show that incorporation of N is crucial for inducing microstructural evolution as well as polycrystalline nano-array formation in high-k oxide under electron irradiation. © IOP Publishing Ltd.
    Original languageEnglish
    Article number15
    Pages (from-to)4379-4383
    JournalNanotechnology
    Volume17
    Issue number17
    DOIs
    Publication statusPublished - 1 Aug 2006

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