Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors

A. Galvan-Gonzalez; G. I. Stegeman; A. K-Y. Jen; X. Wu; M. Canva; A. C. Kowalczyk; X. Q. Zhang; H. S. Lackritz; S. Marder; S. Thayumanavan; G. Levina

doi:10.1364/JOSAB.18.001846

Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors

A. Galvan-Gonzalez, G. I. Stegeman, A. K-Y. Jen, X. Wu, M. Canva, A. C. Kowalczyk, X. Q. Zhang, H. S. Lackritz, S. Marder, S. Thayumanavan, G. Levina

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

37 Citations (Scopus)

Abstract

The photostability of various electro-optic active guest-host polymers, doped with chromophores that possess very efficient cyano-containing acceptors and dialkyamino- or diarylamino- benzenes, and also their extended thiophene analogs as bridging structures, has been investigated over a broad wavelength range in the near infrared and the visible. A variation of over 2 orders of magnitude was found in the probability that an absorbed photon will lead to a photodegraded chromophore. The most photostable chromophore contained a tricyanovinyl acceptor and a diarylaminobenzene bridge unit. © 2001 Optical Society of America.

Original language	English
Pages (from-to)	1846-1853
Journal	Journal of the Optical Society of America B: Optical Physics
Volume	18
Issue number	12
DOIs	https://doi.org/10.1364/JOSAB.18.001846
Publication status	Published - Dec 2001
Externally published	Yes

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Galvan-Gonzalez, A., Stegeman, G. I., Jen, A. K.-Y., Wu, X., Canva, M., Kowalczyk, A. C., Zhang, X. Q., Lackritz, H. S., Marder, S., Thayumanavan, S., & Levina, G. (2001). Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors. Journal of the Optical Society of America B: Optical Physics, 18(12), 1846-1853. https://doi.org/10.1364/JOSAB.18.001846

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title = "Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors",

abstract = "The photostability of various electro-optic active guest-host polymers, doped with chromophores that possess very efficient cyano-containing acceptors and dialkyamino- or diarylamino- benzenes, and also their extended thiophene analogs as bridging structures, has been investigated over a broad wavelength range in the near infrared and the visible. A variation of over 2 orders of magnitude was found in the probability that an absorbed photon will lead to a photodegraded chromophore. The most photostable chromophore contained a tricyanovinyl acceptor and a diarylaminobenzene bridge unit. {\textcopyright} 2001 Optical Society of America.",

author = "A. Galvan-Gonzalez and Stegeman, {G. I.} and Jen, {A. K-Y.} and X. Wu and M. Canva and Kowalczyk, {A. C.} and Zhang, {X. Q.} and Lackritz, {H. S.} and S. Marder and S. Thayumanavan and G. Levina",

year = "2001",

month = dec,

doi = "10.1364/JOSAB.18.001846",

language = "English",

volume = "18",

pages = "1846--1853",

journal = "Journal of the Optical Society of America B: Optical Physics",

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}

Galvan-Gonzalez, A, Stegeman, GI, Jen, AK-Y, Wu, X, Canva, M, Kowalczyk, AC, Zhang, XQ, Lackritz, HS, Marder, S, Thayumanavan, S & Levina, G 2001, 'Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors', Journal of the Optical Society of America B: Optical Physics, vol. 18, no. 12, pp. 1846-1853. https://doi.org/10.1364/JOSAB.18.001846

Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors. / Galvan-Gonzalez, A.; Stegeman, G. I.; Jen, A. K-Y. et al.
In: Journal of the Optical Society of America B: Optical Physics, Vol. 18, No. 12, 12.2001, p. 1846-1853.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors

AU - Galvan-Gonzalez, A.

AU - Stegeman, G. I.

AU - Jen, A. K-Y.

AU - Wu, X.

AU - Canva, M.

AU - Kowalczyk, A. C.

AU - Zhang, X. Q.

AU - Lackritz, H. S.

AU - Marder, S.

AU - Thayumanavan, S.

AU - Levina, G.

PY - 2001/12

Y1 - 2001/12

N2 - The photostability of various electro-optic active guest-host polymers, doped with chromophores that possess very efficient cyano-containing acceptors and dialkyamino- or diarylamino- benzenes, and also their extended thiophene analogs as bridging structures, has been investigated over a broad wavelength range in the near infrared and the visible. A variation of over 2 orders of magnitude was found in the probability that an absorbed photon will lead to a photodegraded chromophore. The most photostable chromophore contained a tricyanovinyl acceptor and a diarylaminobenzene bridge unit. © 2001 Optical Society of America.

AB - The photostability of various electro-optic active guest-host polymers, doped with chromophores that possess very efficient cyano-containing acceptors and dialkyamino- or diarylamino- benzenes, and also their extended thiophene analogs as bridging structures, has been investigated over a broad wavelength range in the near infrared and the visible. A variation of over 2 orders of magnitude was found in the probability that an absorbed photon will lead to a photodegraded chromophore. The most photostable chromophore contained a tricyanovinyl acceptor and a diarylaminobenzene bridge unit. © 2001 Optical Society of America.

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DO - 10.1364/JOSAB.18.001846

M3 - RGC 21 - Publication in refereed journal

SN - 0740-3224

VL - 18

SP - 1846

EP - 1853

JO - Journal of the Optical Society of America B: Optical Physics

JF - Journal of the Optical Society of America B: Optical Physics

IS - 12

ER -

Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors

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