Photoredox Catalysis of Cyclometalated IrIII Complex for the Conversion of Amines to Fluorinated Alkyl Amides
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Related Research Unit(s)
Detail(s)
Original language | English |
---|---|
Pages (from-to) | 1587-1590 |
Journal / Publication | Asian Journal of Organic Chemistry |
Volume | 7 |
Issue number | 8 |
Online published | 8 Jun 2018 |
Publication status | Published - Aug 2018 |
Link(s)
Abstract
Using luminescent cyclometalated IrIII complex as photocatalyst, a new visible‐light induced photocatalytic method for the preparation of perfluorinated alkyl amides under a mild condition has been developed. Primary aliphatic, secondary aliphatic and aromatic amines as well as perfluoroalkyl iodides and bromides can be used as the substrates in the photocatalytic reactions. On the basis of the emission quenching study and the characterizations of the reaction intermediates, the mechanism of the photocatalysis has been proposed.
Research Area(s)
- photoredox catalysis, fluorinated alkyl amides, perfluoroalkyl halides, oxygen, cyclometalated iridium(III) complex, photocatalysis, homogeneous catalysis, iridium
Citation Format(s)
Photoredox Catalysis of Cyclometalated IrIII Complex for the Conversion of Amines to Fluorinated Alkyl Amides. / Ng, Chi-On; Feng, Hua; Cheng, Shun-Cheung et al.
In: Asian Journal of Organic Chemistry, Vol. 7, No. 8, 08.2018, p. 1587-1590.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review