Photoelectron spectroscopic study of iodine- and bromine-treated indium tin oxides and their interfaces with organic films

X. H. Sun, L. F. Cheng, M. W. Liu, L. S. Liao, N. B. Wong, C. S. Lee, S. T. Lee

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

Work function variations of indium tin oxide (ITO) treated with solutions of iodine and bromine as well as bromine vapor were studied by ultraviolet and X-ray photoelectron spectroscopies. Interfaces between the treated ITO and NPB were also investigated. Treatments by iodine and bromine solutions, and bromine vapor led to work function increase by as much as 0.6, 0.7, and 0.9 eV, respectively. After the halogen treatments, the hole-injection barrier for the NPB/ITO contact was remarkably decreased. A light-emitting device fabricated with bromine vapor-treated ITO as anode clearly demonstrated better hole injection at the ITO/NPB interface and a lower drive voltage. © 2003 Elsevier Science B.V. All rights reserved.
Original languageEnglish
Pages (from-to)425-430
JournalChemical Physics Letters
Volume370
Issue number3-4
DOIs
Publication statusPublished - 14 Mar 2003

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