Photocatalytic oxidation of alkenes and alcohols in water by a manganese(v) nitrido complex

Gui Chen; Lingjing Chen; Li Ma; Hoi-Ki Kwong; Tai-Chu Lau

doi:10.1039/c6cc04173f

Photocatalytic oxidation of alkenes and alcohols in water by a manganese(v) nitrido complex

Gui Chen
, Lingjing Chen
, Li Ma
, Hoi-Ki Kwong
, Tai-Chu Lau^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

22 Citations (Scopus)

Abstract

Mn(v) nitrido complex [Mn(N)(CN)₄]^2- is an efficient catalyst for visible-light induced oxidation of alkenes and alcohols in water using [Ru(bpy)₃]²⁺ as a photosensitizer and [Co(NH₃)₅Cl]²⁺ as a sacrificial oxidant. Alkenes are oxidized to epoxides and alcohols to carbonyl compounds.

Original language	English
Pages (from-to)	9271-9274
Journal	Chemical Communications
Volume	52
Issue number	59
Online published	22 Jun 2016
DOIs	https://doi.org/10.1039/c6cc04173f
Publication status	Published - 28 Jul 2016

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title = "Photocatalytic oxidation of alkenes and alcohols in water by a manganese(v) nitrido complex",

abstract = "Mn(v) nitrido complex [Mn(N)(CN)4]2- is an efficient catalyst for visible-light induced oxidation of alkenes and alcohols in water using [Ru(bpy)3]2+ as a photosensitizer and [Co(NH3)5Cl]2+ as a sacrificial oxidant. Alkenes are oxidized to epoxides and alcohols to carbonyl compounds.",

author = "Gui Chen and Lingjing Chen and Li Ma and Hoi-Ki Kwong and Tai-Chu Lau",

year = "2016",

month = jul,

day = "28",

doi = "10.1039/c6cc04173f",

language = "English",

volume = "52",

pages = "9271--9274",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Photocatalytic oxidation of alkenes and alcohols in water by a manganese(v) nitrido complex

AU - Chen, Gui

AU - Chen, Lingjing

AU - Ma, Li

AU - Kwong, Hoi-Ki

AU - Lau, Tai-Chu

PY - 2016/7/28

Y1 - 2016/7/28

N2 - Mn(v) nitrido complex [Mn(N)(CN)4]2- is an efficient catalyst for visible-light induced oxidation of alkenes and alcohols in water using [Ru(bpy)3]2+ as a photosensitizer and [Co(NH3)5Cl]2+ as a sacrificial oxidant. Alkenes are oxidized to epoxides and alcohols to carbonyl compounds.

AB - Mn(v) nitrido complex [Mn(N)(CN)4]2- is an efficient catalyst for visible-light induced oxidation of alkenes and alcohols in water using [Ru(bpy)3]2+ as a photosensitizer and [Co(NH3)5Cl]2+ as a sacrificial oxidant. Alkenes are oxidized to epoxides and alcohols to carbonyl compounds.

UR - https://www.scopus.com/pages/publications/84978689249

UR - https://www.scopus.com/pages/publications/84978689249#tab=impact

U2 - 10.1039/c6cc04173f

DO - 10.1039/c6cc04173f

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 52

SP - 9271

EP - 9274

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Photocatalytic oxidation of alkenes and alcohols in water by a manganese(v) nitrido complex

Abstract

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