Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups

Juan‐Carlos Rodriguz‐Ubis; Béatrice Alpha; Dominique Plancherel; Jean‐Marie Lehn

doi:10.1002/hlca.19840670833

Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups

Juan‐Carlos Rodriguz‐Ubis
, Béatrice Alpha
, Dominique Plancherel
, Jean‐Marie Lehn

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

240 Citations (Scopus)

Abstract

The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, i.e, of [bpy.bpy.bpy] 1 [bpy.bpy.phen] 2 [phen.phen.‐phen] 3 [2.1.phen] 4 and [2.2.phen] 5, have been prepared. 1, 2, 4 and 5 have been obtained in high yield by condensation of bis(bromomethyl)bipyridine 6 or ‐phenanthroline 9 with the corresponding macrocyclic diamines in presence of Na<sub>2</sub>CO<sub>3</sub>. Direct access to the NaBr complexes of th symmetrical cryptands 1 and 3 was achieved by a one‐step macrobicyclisation procedure. The metal‐ion complexes of ligands 1‐5 have the attractive feature of combining the cation inclusion, nature of cryptates with the photoactivity of bipyridine and phenanthroline groups; they may thus be expected to posses a variety of interesting physical and chemical properties. Copyright © 1984 Verlag GmbH & Co. KGaA, Weinheim

Original language	English
Pages (from-to)	2264-2269
Journal	Helvetica Chimica Acta
Volume	67
Issue number	8
DOIs	https://doi.org/10.1002/hlca.19840670833
Publication status	Published - 19 Dec 1984
Externally published	Yes

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@article{1b77c70618564db0811e97fe17b74839,

title = "Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups",

abstract = "The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, i.e, of [bpy.bpy.bpy] 1 [bpy.bpy.phen] 2 [phen.phen.‐phen] 3 [2.1.phen] 4 and [2.2.phen] 5, have been prepared. 1, 2, 4 and 5 have been obtained in high yield by condensation of bis(bromomethyl)bipyridine 6 or ‐phenanthroline 9 with the corresponding macrocyclic diamines in presence of Na2CO3. Direct access to the NaBr complexes of th symmetrical cryptands 1 and 3 was achieved by a one‐step macrobicyclisation procedure. The metal‐ion complexes of ligands 1‐5 have the attractive feature of combining the cation inclusion, nature of cryptates with the photoactivity of bipyridine and phenanthroline groups; they may thus be expected to posses a variety of interesting physical and chemical properties. Copyright {\textcopyright} 1984 Verlag GmbH \& Co. KGaA, Weinheim",

author = "Juan‐Carlos Rodriguz‐Ubis and B{\'e}atrice Alpha and Dominique Plancherel and Jean‐Marie Lehn",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

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Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups. / Rodriguz‐Ubis, Juan‐Carlos; Alpha, Béatrice; Plancherel, Dominique et al.
In: Helvetica Chimica Acta, Vol. 67, No. 8, 19.12.1984, p. 2264-2269.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups

AU - Rodriguz‐Ubis, Juan‐Carlos

AU - Alpha, Béatrice

AU - Plancherel, Dominique

AU - Lehn, Jean‐Marie

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 1984/12/19

Y1 - 1984/12/19

N2 - The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, i.e, of [bpy.bpy.bpy] 1 [bpy.bpy.phen] 2 [phen.phen.‐phen] 3 [2.1.phen] 4 and [2.2.phen] 5, have been prepared. 1, 2, 4 and 5 have been obtained in high yield by condensation of bis(bromomethyl)bipyridine 6 or ‐phenanthroline 9 with the corresponding macrocyclic diamines in presence of Na2CO3. Direct access to the NaBr complexes of th symmetrical cryptands 1 and 3 was achieved by a one‐step macrobicyclisation procedure. The metal‐ion complexes of ligands 1‐5 have the attractive feature of combining the cation inclusion, nature of cryptates with the photoactivity of bipyridine and phenanthroline groups; they may thus be expected to posses a variety of interesting physical and chemical properties. Copyright © 1984 Verlag GmbH & Co. KGaA, Weinheim

AB - The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, i.e, of [bpy.bpy.bpy] 1 [bpy.bpy.phen] 2 [phen.phen.‐phen] 3 [2.1.phen] 4 and [2.2.phen] 5, have been prepared. 1, 2, 4 and 5 have been obtained in high yield by condensation of bis(bromomethyl)bipyridine 6 or ‐phenanthroline 9 with the corresponding macrocyclic diamines in presence of Na2CO3. Direct access to the NaBr complexes of th symmetrical cryptands 1 and 3 was achieved by a one‐step macrobicyclisation procedure. The metal‐ion complexes of ligands 1‐5 have the attractive feature of combining the cation inclusion, nature of cryptates with the photoactivity of bipyridine and phenanthroline groups; they may thus be expected to posses a variety of interesting physical and chemical properties. Copyright © 1984 Verlag GmbH & Co. KGaA, Weinheim

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DO - 10.1002/hlca.19840670833

M3 - RGC 21 - Publication in refereed journal

SN - 0018-019X

VL - 67

SP - 2264

EP - 2269

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 8

ER -

Photoactive cryptands. Synthesis of the sodium cryptates of macrobicyclic ligands containing bipyridine and phenoanthroline groups

Abstract

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