Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand

Aimery Caron; Jean Guilhelm; Claude Riche; Claudine Pascard; Béatrice Alpha; Jean‐Marie Lehn; Juan‐Carlos Rodriguez‐Ubis

doi:10.1002/hlca.19850680609

Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand

Aimery Caron
, Jean Guilhelm
, Claude Riche
, Claudine Pascard
, Béatrice Alpha
, Jean‐Marie Lehn
, Juan‐Carlos Rodriguez‐Ubis

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

58 Citations (Scopus)

Abstract

The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl<sub>3</sub> of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na<sup>+</sup> cation being contained in the molecular cavity of 1 and coordinated to all eight N‐atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms. Copyright © 1985 Verlag GmbH & Co. KGaA, Weinheim

Original language	English
Pages (from-to)	1577-1582
Journal	Helvetica Chimica Acta
Volume	68
Issue number	6
DOIs	https://doi.org/10.1002/hlca.19850680609
Publication status	Published - 25 Sept 1985
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

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title = "Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand",

abstract = "The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl3 of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na+ cation being contained in the molecular cavity of 1 and coordinated to all eight N‐atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms. Copyright {\textcopyright} 1985 Verlag GmbH \& Co. KGaA, Weinheim",

author = "Aimery Caron and Jean Guilhelm and Claude Riche and Claudine Pascard and B{\'e}atrice Alpha and Jean‐Marie Lehn and Juan‐Carlos Rodriguez‐Ubis",

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T1 - Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand

AU - Caron, Aimery

AU - Guilhelm, Jean

AU - Riche, Claude

AU - Pascard, Claudine

AU - Alpha, Béatrice

AU - Lehn, Jean‐Marie

AU - Rodriguez‐Ubis, Juan‐Carlos

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N2 - The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl3 of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na+ cation being contained in the molecular cavity of 1 and coordinated to all eight N‐atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms. Copyright © 1985 Verlag GmbH & Co. KGaA, Weinheim

AB - The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl3 of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na+ cation being contained in the molecular cavity of 1 and coordinated to all eight N‐atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms. Copyright © 1985 Verlag GmbH & Co. KGaA, Weinheim

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DO - 10.1002/hlca.19850680609

M3 - RGC 21 - Publication in refereed journal

SN - 0018-019X

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SP - 1577

EP - 1582

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 6

ER -

Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand

Abstract

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