Perspective on inorganic electron donor-mediated biological denitrification process for low C/N wastewaters

Nitrate is the most common water environmental pollutant in the world. Inorganic electron donor-mediated denitrification is a typical process with significant advantages in treating low carbon–nitrogen ratio water and wastewater and has attracted extensive research attention. This review summarizes the denitrification processes using inorganic substances, including hydrogen, reductive sulfur compounds, zero-valent iron, and iron oxides, ammonium nitrogen, and other reductive heavy metal ions as electron donors. Aspects on the functional microorganisms, critical metabolic pathways, limiting factors and mathematical modeling are outlined. Also, the typical inorganic electron donor-mediated denitrification processes and their mechanism, the available microorganisms, process enhancing approaches and the engineering potentials, are compared and discussed. Finally, the prospects of developing the next generation inorganic electron donor-mediated denitrification process is put forward.