TY - JOUR
T1 - Pd catalyst supported on a chitosan-functionalized large-area 3D reduced graphene oxide for formic acid electrooxidation reaction
AU - Wang, Yi
AU - Liu, Huili
AU - Wang, Li
AU - Wang, Haibo
AU - Du, Xuan
AU - Wang, Fang
AU - Qi, Tao
AU - Lee, Jong-Min
AU - Wang, Xin
N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].
PY - 2013/6/21
Y1 - 2013/6/21
N2 - A large-area three-dimensional (3D) reduced graphene oxide (TRGO) material was obtained by facile heat treatment of a two-dimensional (2D) reduced graphene oxide (RGO) material. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption results reveal that the new material is composed of small and fluffy graphene nanosheets, with many graphene arrays as well as 3D interconnected macropores and mesopores in some local positions, and possesses an ultrahigh specific surface area (>1000 m2 g-1) and large pore volume. The material was used to support a Pd catalyst for formic acid electrooxidation, demonstrating a much better electrocatalytic activity in terms of the onset potential and peak current density (seven times larger) than that of conventional carbon black, the most popular catalyst support. To tailor the electronic properties, the TRGO material was further functionalized with chitosan (CS). Compared to the Pd loaded on TRGO, Pd nanoparticles supported on the CS-functionalized TRGO show a better catalytic activity and good stability. This work provides a promising catalyst support material for direct formic acid fuel cells. © 2013 The Royal Society of Chemistry.
AB - A large-area three-dimensional (3D) reduced graphene oxide (TRGO) material was obtained by facile heat treatment of a two-dimensional (2D) reduced graphene oxide (RGO) material. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption results reveal that the new material is composed of small and fluffy graphene nanosheets, with many graphene arrays as well as 3D interconnected macropores and mesopores in some local positions, and possesses an ultrahigh specific surface area (>1000 m2 g-1) and large pore volume. The material was used to support a Pd catalyst for formic acid electrooxidation, demonstrating a much better electrocatalytic activity in terms of the onset potential and peak current density (seven times larger) than that of conventional carbon black, the most popular catalyst support. To tailor the electronic properties, the TRGO material was further functionalized with chitosan (CS). Compared to the Pd loaded on TRGO, Pd nanoparticles supported on the CS-functionalized TRGO show a better catalytic activity and good stability. This work provides a promising catalyst support material for direct formic acid fuel cells. © 2013 The Royal Society of Chemistry.
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U2 - 10.1039/c3ta10214a
DO - 10.1039/c3ta10214a
M3 - RGC 21 - Publication in refereed journal
SN - 2050-7488
VL - 1
SP - 6839
EP - 6848
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
IS - 23
ER -
