Palladium-catalyzed asymmetric reductive Heck reaction of aryl halides
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 6531-6535 |
| Journal / Publication | Angewandte Chemie - International Edition |
| Volume | 54 |
| Issue number | 22 |
| Online published | 13 Apr 2015 |
| Publication status | Published - May 2015 |
| Externally published | Yes |
Link(s)
Abstract
Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
Research Area(s)
- asymmetric catalysis, hydrogen bonding, olefins, palladium, synthetic methods
Citation Format(s)
Palladium-catalyzed asymmetric reductive Heck reaction of aryl halides. / Yue, Guizhou; Lei, Kaining; Hirao, Hajime et al.
In: Angewandte Chemie - International Edition, Vol. 54, No. 22, 05.2015, p. 6531-6535.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
