Palladium-catalyzed asymmetric reductive Heck reaction of aryl halides

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)6531-6535
Journal / PublicationAngewandte Chemie - International Edition
Volume54
Issue number22
Online published13 Apr 2015
Publication statusPublished - May 2015
Externally publishedYes

Abstract

Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.

Research Area(s)

  • asymmetric catalysis, hydrogen bonding, olefins, palladium, synthetic methods

Citation Format(s)

Palladium-catalyzed asymmetric reductive Heck reaction of aryl halides. / Yue, Guizhou; Lei, Kaining; Hirao, Hajime; Zhou, Jianrong(Steve).

In: Angewandte Chemie - International Edition, Vol. 54, No. 22, 05.2015, p. 6531-6535.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review