Palladium-based kinetic resolution of racemic tosylaziridines

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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Author(s)

  • Wa-Hung Leung
  • Wing-Leung Mak
  • Eddie Y. Y. Chan
  • Tony C. H. Lam
  • Wing-Sze Lee
  • Lam-Lung Yeung

Detail(s)

Original languageEnglish
Pages (from-to)1688-1690
Journal / PublicationSynlett
Issue number10
Publication statusPublished - 2002

Link(s)

DOI

DOI
Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-0036401538&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(48cdb11a-69b4-414a-a7e5-ac301e6594db).html

Abstract

Dicationic Pd(II) complexes with chiral pyridine bis(oxazoline) ligands are catalysts for kinetic resolution of racemic styrene tosylazirdines, Treatment of styrene tosylaziridine with 0.5 equivalents of alcohol in the presence of the chiral Pd catalyst affords β-alkoxy tosylamide with ee up to 71%.

Research Area(s)

  • Alcoholysis, Asymmetric, Aziridine, Kinetic resolution, Palladium

Fingerprint

Publication fingerprints text

100
kinetics INIS
100
resolution INIS
100
catalysts INIS
100
chirality INIS
100
palladium INIS
100
styrene INIS
100
Styrene Keyphrases
100
Racemic Keyphrases
100
Kinetic Resolution Keyphrases
100
Palladium-based Keyphrases
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Citation Format(s)

[ RIS ] [ BibTeX ]
Palladium-based kinetic resolution of racemic tosylaziridines. / Leung, Wa-Hung; Mak, Wing-Leung; Chan, Eddie Y. Y. et al.
In: Synlett, No. 10, 2002, p. 1688-1690.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review