Oxygen evolution from BF3/MnO4-

Shek-Man Yiu; Wai-Lun Man; Xin Wang; William W. Y. Lam; Siu-Mui Ng; Hoi-Ki Kwong; Kai-Chung Lau; Tai-Chu Lau

doi:10.1039/c1cc00019e

Oxygen evolution from BF3/MnO4-

Shek-Man Yiu, Wai-Lun Man, Xin Wang, William W. Y. Lam, Siu-Mui Ng, Hoi-Ki Kwong, Kai-Chung Lau, Tai-Chu Lau

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

15 Citations (Scopus)

Abstract

MnO₄^- is activated by BF₃ to undergo intramolecular coupling of two oxo ligands to generate O₂. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO₂(OBF₃)₂]^- to the O⋯O coupling transition state. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	4159-4161
Journal	Chemical Communications
Volume	47
Issue number	14
DOIs	https://doi.org/10.1039/c1cc00019e
Publication status	Published - 2011

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title = "Oxygen evolution from BF3/MnO4-",

abstract = "MnO4- is activated by BF3 to undergo intramolecular coupling of two oxo ligands to generate O2. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO2(OBF3)2]- to the O⋯O coupling transition state. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Shek-Man Yiu and Wai-Lun Man and Xin Wang and Lam, {William W. Y.} and Siu-Mui Ng and Hoi-Ki Kwong and Kai-Chung Lau and Tai-Chu Lau",

year = "2011",

doi = "10.1039/c1cc00019e",

language = "English",

volume = "47",

pages = "4159--4161",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Oxygen evolution from BF3/MnO4-

AU - Yiu, Shek-Man

AU - Man, Wai-Lun

AU - Wang, Xin

AU - Lam, William W. Y.

AU - Ng, Siu-Mui

AU - Kwong, Hoi-Ki

AU - Lau, Kai-Chung

AU - Lau, Tai-Chu

PY - 2011

Y1 - 2011

N2 - MnO4- is activated by BF3 to undergo intramolecular coupling of two oxo ligands to generate O2. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO2(OBF3)2]- to the O⋯O coupling transition state. © 2011 The Royal Society of Chemistry.

AB - MnO4- is activated by BF3 to undergo intramolecular coupling of two oxo ligands to generate O2. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO2(OBF3)2]- to the O⋯O coupling transition state. © 2011 The Royal Society of Chemistry.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-79954992139&origin=recordpage

U2 - 10.1039/c1cc00019e

DO - 10.1039/c1cc00019e

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 47

SP - 4159

EP - 4161

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Oxygen evolution from BF3/MnO4-

Abstract

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