Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide using a luminescent Os(vi) cyanonitrido complex
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
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Detail(s)
Original language | English |
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Pages (from-to) | 7988-7991 |
Journal / Publication | Chemical Communications |
Volume | 58 |
Issue number | 57 |
Online published | 20 Jun 2022 |
Publication status | Published - 21 Jul 2022 |
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Abstract
The photoreactions of a luminescent osmium(vi) nitrido complex, [OsVI(N)(L)(CN)3]− (OsN, HL = 2-(2-hydroxy-5-nitrophenyl)benzoxazole), with catechol (H2Cat) and hydroquinone (H2Q) lead to the cleavage of strong C-OH bonds (ca. 120 kcal mol−1) of the dihydroxybenzenes with concomitant conversion of the coordinated cyanide to carbon monoxide.
Citation Format(s)
Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide using a luminescent Os(vi) cyanonitrido complex. / Xiang, Jing; Zhu, Jiang; Zhou, Miaomiao et al.
In: Chemical Communications, Vol. 58, No. 57, 21.07.2022, p. 7988-7991.
In: Chemical Communications, Vol. 58, No. 57, 21.07.2022, p. 7988-7991.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review