Abstract
Quaternary Ti-B-C-N coatings with different carbon concentrations are deposited on high-speed steel substrates by reactive magnetron sputtering. The oxidation behavior between 300 and 800°C under ambient conditions is studied by scanning electron microscopy, high-resolution transmission electron microscopy, Vickers micro-hardness, and X-ray diffraction. The Ti-B-C-N coatings with smaller carbon contents have better oxidation resistance and the oxidation process can be divided into two stages: low-speed oxidation below 700°C and high-speed oxidation above 700°C. An oxidation mechanism is proposed to explain the relationship between the reaction with oxygen and observed oxidation behavior. © 2012 Elsevier Ltd. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 1505-1512 |
| Journal | Vacuum |
| Volume | 86 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 27 Apr 2012 |
Research Keywords
- Oxidation behavior
- Reactive magnetron sputtering
- Ti-B-C-N coatings
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