Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 9724-9726 |
Journal / Publication | Inorganic Chemistry |
Volume | 47 |
Issue number | 21 |
Online published | 2 Oct 2008 |
Publication status | Published - 3 Nov 2008 |
Externally published | Yes |
Link(s)
Abstract
Using predesigned tetrahedral quadridentate linker tetrakis(4- pyridyloxymethylene)methane (TPOM) as the organic linker, tetrahedral P1 clusters ([Cd8S(SPh)16]2-) and C1 clusters ([Cd17S4(SPh)28]2-) have been assembled into beltlike (MCOF-9) or chainlike (MCOF-10) configurations, as determined by single-crystal X-ray diffraction. The onset of optical absorptions of MCOF-9 and MCOF-10 is around 400 and 420 nm, respectively. The thermal analysis shows that both materials are stable up to 250 °C. © 2008 American Chemical Society.
Citation Format(s)
Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker. / Zhang, Qichun; Bu, Xianhui; Lin, Zhien; Wu, Tao; Feng, Pingyun.
In: Inorganic Chemistry, Vol. 47, No. 21, 03.11.2008, p. 9724-9726.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review