Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker

Qichun Zhang; Xianhui Bu; Zhien Lin; Tao Wu; Pingyun Feng

doi:10.1021/ic800588q

Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker

Qichun Zhang, Xianhui Bu, Zhien Lin, Tao Wu, Pingyun Feng^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

102 Citations (Scopus)

Abstract

Using predesigned tetrahedral quadridentate linker tetrakis(4- pyridyloxymethylene)methane (TPOM) as the organic linker, tetrahedral P1 clusters ([Cd₈S(SPh)₁₆]^2-) and C1 clusters ([Cd₁₇S₄(SPh)₂₈]^2-) have been assembled into beltlike (MCOF-9) or chainlike (MCOF-10) configurations, as determined by single-crystal X-ray diffraction. The onset of optical absorptions of MCOF-9 and MCOF-10 is around 400 and 420 nm, respectively. The thermal analysis shows that both materials are stable up to 250 °C. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	9724-9726
Journal	Inorganic Chemistry
Volume	47
Issue number	21
Online published	2 Oct 2008
DOIs	https://doi.org/10.1021/ic800588q
Publication status	Published - 3 Nov 2008
Externally published	Yes

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title = "Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker",

abstract = "Using predesigned tetrahedral quadridentate linker tetrakis(4- pyridyloxymethylene)methane (TPOM) as the organic linker, tetrahedral P1 clusters ([Cd8S(SPh)16]2-) and C1 clusters ([Cd17S4(SPh)28]2-) have been assembled into beltlike (MCOF-9) or chainlike (MCOF-10) configurations, as determined by single-crystal X-ray diffraction. The onset of optical absorptions of MCOF-9 and MCOF-10 is around 400 and 420 nm, respectively. The thermal analysis shows that both materials are stable up to 250 °C. {\textcopyright} 2008 American Chemical Society.",

author = "Qichun Zhang and Xianhui Bu and Zhien Lin and Tao Wu and Pingyun Feng",

year = "2008",

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doi = "10.1021/ic800588q",

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volume = "47",

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T1 - Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker

AU - Zhang, Qichun

AU - Bu, Xianhui

AU - Lin, Zhien

AU - Wu, Tao

AU - Feng, Pingyun

PY - 2008/11/3

Y1 - 2008/11/3

N2 - Using predesigned tetrahedral quadridentate linker tetrakis(4- pyridyloxymethylene)methane (TPOM) as the organic linker, tetrahedral P1 clusters ([Cd8S(SPh)16]2-) and C1 clusters ([Cd17S4(SPh)28]2-) have been assembled into beltlike (MCOF-9) or chainlike (MCOF-10) configurations, as determined by single-crystal X-ray diffraction. The onset of optical absorptions of MCOF-9 and MCOF-10 is around 400 and 420 nm, respectively. The thermal analysis shows that both materials are stable up to 250 °C. © 2008 American Chemical Society.

AB - Using predesigned tetrahedral quadridentate linker tetrakis(4- pyridyloxymethylene)methane (TPOM) as the organic linker, tetrahedral P1 clusters ([Cd8S(SPh)16]2-) and C1 clusters ([Cd17S4(SPh)28]2-) have been assembled into beltlike (MCOF-9) or chainlike (MCOF-10) configurations, as determined by single-crystal X-ray diffraction. The onset of optical absorptions of MCOF-9 and MCOF-10 is around 400 and 420 nm, respectively. The thermal analysis shows that both materials are stable up to 250 °C. © 2008 American Chemical Society.

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U2 - 10.1021/ic800588q

DO - 10.1021/ic800588q

M3 - RGC 21 - Publication in refereed journal

SN - 0020-1669

VL - 47

SP - 9724

EP - 9726

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker

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