TY - JOUR
T1 - Organic metals
T2 - Conducting complexes of poly(2,5-thienylene sulphide) and poly(2,5-thienylene selenide)
AU - Jen, Kwan-Yue
AU - Benfaremo, Nicholas
AU - Cava, Michael P.
AU - Huang, Wu-Song
AU - MacDiarmid, A. G.
PY - 1983
Y1 - 1983
N2 - Exposure of highly purified samples of the new polymers poly(2,5-thienylene selenide) (PTSe) and poly(2,5-thienylene sulphide) (PTS) to arsenic pentafluoride afforded a conducting complex (0.12 S/cm) from PTSe but only a moderately conducting complex (ca. 10-5 S/cm) from PTS, a result which is in direct contrast to the behaviour of poly(p-phenylene selenide) and poly(p-phenylene sulphide) upon similar treatment.
AB - Exposure of highly purified samples of the new polymers poly(2,5-thienylene selenide) (PTSe) and poly(2,5-thienylene sulphide) (PTS) to arsenic pentafluoride afforded a conducting complex (0.12 S/cm) from PTSe but only a moderately conducting complex (ca. 10-5 S/cm) from PTS, a result which is in direct contrast to the behaviour of poly(p-phenylene selenide) and poly(p-phenylene sulphide) upon similar treatment.
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M3 - RGC 22 - Publication in policy or professional journal
SN - 0577-6171
SP - 633
EP - 634
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 11
ER -