Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Michael Le Breton
  • Yujue Wang
  • Asa M. Hallquist
  • Ravi Kant Pathak
  • Jing Zheng
  • Yudong Yang
  • Dongjie Shang
  • Marianne Glasius
  • Thomas J. Bannan
  • Qianyun Liu
  • Carl J. Percival
  • Wenfei Zhu
  • Shengrong Lou
  • David Topping
  • Yuchen Wang
  • Jianzhen Yu
  • Keding Lu
  • Song Guo
  • Min Hu
  • Mattias Hallquist

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Detail(s)

Original languageEnglish
Pages (from-to)10355-10371
Journal / PublicationAtmospheric Chemistry and Physics
Volume18
Issue number14
Online published19 Jul 2018
Publication statusPublished - 2018

Link(s)

Abstract

A time-of-flight chemical ionization mass spectrometer (CIMS) utilizing the Filter Inlet for Gas and Aerosol (FIGAERO) was deployed at a regional site 40 km north-west of Beijing and successfully identified and measured 17 sulfur-containing organics (SCOs are organo/nitrooxy organosulfates and sulfonates) with biogenic and anthropogenic precursors. The SCOs were quantified using laboratory-synthesized standards of lactic acid sulfate and nitrophenol organosulfate (NP OS). The variation in field observations was confirmed by comparison to offline measurement techniques (orbitrap and high-performance liquid chromatography, HPLC) using daily averages. The mean total (of the 17 identified by CIMS) SCO particle mass concentration was 210 ± 110 ng mg-3 and had a maximum of 540 ng mg-3, although it contributed to only 2 ± 1 % of the organic aerosol (OA). The CIMS identified a persistent gas-phase presence of SCOs in the ambient air, which was further supported by separate vapour-pressure measurements of NP OS by a Knudsen Effusion Mass Spectrometer (KEMS). An increase in relative humidity (RH) promoted partitioning of SCO to the particle phase, whereas higher temperatures favoured higher gas-phase concentrations. Biogenic emissions contributed to only 19 % of total SCOs measured in this study. Here, C10H16NSO7, a monoterpene-derived SCO, represented the highest fraction (10 %) followed by an isoprene-derived SCO. The anthropogenic SCOs with polycyclic aromatic hydrocarbon (PAH) and aromatic precursors dominated the SCO mass loading (51 %) with C11H11SO7, derived from methyl naphthalene oxidation, contributing to 40 ng mg-3 and 0.3 % of the OA mass. Anthropogenic-related SCOs correlated well with benzene, although their abundance depended highly on the photochemical age of the air mass, tracked using the ratio between pinonic acid and its oxidation product, acting as a qualitative photochemical clock. In addition to typical anthropogenic and biogenic precursors the biomass-burning precursor nitrophenol (NP) provided a significant level of NP OS. It must be noted that the contribution analysis here is only representative of the detected SCOs. There are likely to be many more SCOs present which the CIMS has not identified. Gas- and particle-phase measurements of glycolic acid suggest that partitioning towards the particle phase promotes glycolic acid sulfate production, contrary to the current formation mechanism suggested in the literature. Furthermore, the HSO4 ... H2SO4g- cluster measured by the CIMS was utilized as a qualitative marker for acidity and indicates that the production of total SCOs is efficient in highly acidic aerosols with high SO42g- and organic content. This dependency becomes more complex when observing individual SCOs due to variability of specific VOC precursors.

Research Area(s)

Citation Format(s)

Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS. / Le Breton, Michael; Wang, Yujue; Hallquist, Asa M.; Kant Pathak, Ravi; Zheng, Jing; Yang, Yudong; Shang, Dongjie; Glasius, Marianne; Bannan, Thomas J.; Liu, Qianyun; Chan, Chak K.; Percival, Carl J.; Zhu, Wenfei; Lou, Shengrong; Topping, David; Wang, Yuchen; Yu, Jianzhen; Lu, Keding; Guo, Song; Hu, Min; Hallquist, Mattias.

In: Atmospheric Chemistry and Physics, Vol. 18, No. 14, 2018, p. 10355-10371.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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