One-Step Synthesis of Mixed Lanthanide Metal–Organic Framework Films for Sensitive Temperature Mapping
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Related Research Unit(s)
Detail(s)
Original language | English |
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Article number | 1900336 |
Journal / Publication | Advanced Optical Materials |
Volume | 7 |
Issue number | 19 |
Online published | 19 Jun 2019 |
Publication status | Published - 4 Oct 2019 |
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Abstract
Mixed lanthanide metal–organic framework (LnMOF) films are directly grown on a quartz substrate through a wet chemical synthesis. Thermometric properties of the LnMOF films originating from temperature dependent emission intensity ratio of Tb/Eu are systematically investigated in the 298–383 K range. At an optimized Tb/Eu concentration ratio of 98.0:2.0, the ratiometric thermometer registers a high relative sensitivity of 16.14% K−1 at 359 K. As the temperature increases from 298 to 383 K, the LnMOF film thermometer also displays a distinct change in emission color from green to red, corresponding to a shift in Commission International de l'Eclairage (CIE) chromaticity coordinates from (0.3882, 0.5271) to (0.5459, 0.4037). The colorimetric property of the LnMOF film thermometer is exploited for real-time temperature mapping with a high sensitivity.
Research Area(s)
- energy transfer, luminescence thermometry, metal–organic frameworks, thermal mapping, thermometers, thin films
Citation Format(s)
One-Step Synthesis of Mixed Lanthanide Metal–Organic Framework Films for Sensitive Temperature Mapping. / Yang, Xueqing; Zou, Hua; Sun, Xinwen et al.
In: Advanced Optical Materials, Vol. 7, No. 19, 1900336, 04.10.2019.
In: Advanced Optical Materials, Vol. 7, No. 19, 1900336, 04.10.2019.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review