One-pot synthesis of uniform Fe3O4 nanospheres with carbon matrix support for improved lithium storage capabilities

Jun Song Chen; Yumiao Zhang; Xiong Wen Lou

doi:10.1021/am201079z

One-pot synthesis of uniform Fe₃O₄ nanospheres with carbon matrix support for improved lithium storage capabilities

Jun Song Chen
, Yumiao Zhang
, Xiong Wen Lou

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

161 Citations (Scopus)

Abstract

Poly(acrylic acid) (PAA)-entangled Fe₃O₄ nanospheres are synthesized via a facile solvothermal method. In this system, ethylenediamine plays a very important role to control the uniformity of the nanospheres, and the PAA molecules serve as the carbon source that transforms into a carbon matrix after the heat treatment under an inert atmosphere. These uniform Fe₃O₄ nanospheres with carbon matrix support manifest greatly enhanced lithium storage properties over prolonged cycling, with a reversible capacity of 712 mA h g^-1 retained after 60 charge/discharge cycles. However, the carbon-free counterpart can only deliver a much lower capacity of 328 mA h g^-1. © 2011 American Chemical Society.

Original language	English
Pages (from-to)	3276-3279
Journal	ACS Applied Materials and Interfaces
Volume	3
Issue number	9
DOIs	https://doi.org/10.1021/am201079z
Publication status	Published - 28 Sept 2011
Externally published	Yes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Research Keywords

anode
carbon matrix
Fe3O4
lithium-ion batteries

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Cite this

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title = "One-pot synthesis of uniform Fe3O4 nanospheres with carbon matrix support for improved lithium storage capabilities",

abstract = "Poly(acrylic acid) (PAA)-entangled Fe3O4 nanospheres are synthesized via a facile solvothermal method. In this system, ethylenediamine plays a very important role to control the uniformity of the nanospheres, and the PAA molecules serve as the carbon source that transforms into a carbon matrix after the heat treatment under an inert atmosphere. These uniform Fe3O4 nanospheres with carbon matrix support manifest greatly enhanced lithium storage properties over prolonged cycling, with a reversible capacity of 712 mA h g-1 retained after 60 charge/discharge cycles. However, the carbon-free counterpart can only deliver a much lower capacity of 328 mA h g-1. {\textcopyright} 2011 American Chemical Society.",

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AU - Chen, Jun Song

AU - Zhang, Yumiao

AU - Lou, Xiong Wen

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

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N2 - Poly(acrylic acid) (PAA)-entangled Fe3O4 nanospheres are synthesized via a facile solvothermal method. In this system, ethylenediamine plays a very important role to control the uniformity of the nanospheres, and the PAA molecules serve as the carbon source that transforms into a carbon matrix after the heat treatment under an inert atmosphere. These uniform Fe3O4 nanospheres with carbon matrix support manifest greatly enhanced lithium storage properties over prolonged cycling, with a reversible capacity of 712 mA h g-1 retained after 60 charge/discharge cycles. However, the carbon-free counterpart can only deliver a much lower capacity of 328 mA h g-1. © 2011 American Chemical Society.

AB - Poly(acrylic acid) (PAA)-entangled Fe3O4 nanospheres are synthesized via a facile solvothermal method. In this system, ethylenediamine plays a very important role to control the uniformity of the nanospheres, and the PAA molecules serve as the carbon source that transforms into a carbon matrix after the heat treatment under an inert atmosphere. These uniform Fe3O4 nanospheres with carbon matrix support manifest greatly enhanced lithium storage properties over prolonged cycling, with a reversible capacity of 712 mA h g-1 retained after 60 charge/discharge cycles. However, the carbon-free counterpart can only deliver a much lower capacity of 328 mA h g-1. © 2011 American Chemical Society.

KW - anode

KW - carbon matrix

KW - Fe3O4

KW - lithium-ion batteries

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JO - ACS Applied Materials and Interfaces

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