On the timing of hydrolysis / reoxidation in the osmium-catalyzed asymmetric dihydroxylation of olefins using potassium ferricyanide as the reoxidant

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)3965-3968
Journal / PublicationTetrahedron Letters
Volume32
Issue number32
Publication statusPublished - 5 Aug 1991
Externally publishedYes

Abstract

Hydrolysis is shown to precede reoxidation in the catalytic cycle for the asymmetric dihydroxylation of olefins using potassium ferricyanide as the stoichiometric reoxidant, thereby accounting for the observed absence of a non-enantioselective "second cycle.". © 1991.

Citation Format(s)

On the timing of hydrolysis / reoxidation in the osmium-catalyzed asymmetric dihydroxylation of olefins using potassium ferricyanide as the reoxidant. / Ogino, Yasukazu; Chen, Hou; Kwong, Hoi-Lun; Sharpless, K.Barry.

In: Tetrahedron Letters, Vol. 32, No. 32, 05.08.1991, p. 3965-3968.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review