Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang; Lap Szeto; Wesley Ting Kwok Chan; Ho-Lun Yeung; Ka-Leung Wong; Wing-Tak Wong

doi:10.1139/v11-132

Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang
, Lap Szeto
, Wesley Ting Kwok Chan
, Ho-Lun Yeung
, Ka-Leung Wong
, Wing-Tak Wong

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

1 Citation (Scopus)

Abstract

Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn ₂(L1) ₂(L2) ₂] _∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn ₂(L1) ₂(L3) ₂] _∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å ³ that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.

Original language	English
Pages (from-to)	100-107
Journal	Canadian Journal of Chemistry
Volume	90
Issue number	1
DOIs	https://doi.org/10.1139/v11-132
Publication status	Published - Jan 2012
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

1,2-bis(4-pyridyl)hydrazine
Coordination polymer
Hydrogen bond
Interpenetrating polymer
Metal organic framework
Microporous

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@article{b723a11e823241c7b4f5dbbf7dc65850,

title = "Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network",

abstract = "Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 {\AA} 3 that occupies 34.1\% of the unit cell. {\textcopyright} 2011 Published by NRC Research Press.",

keywords = "1,2-bis(4-pyridyl)hydrazine, Coordination polymer, Hydrogen bond, Interpenetrating polymer, Metal organic framework, Microporous",

author = "Huaishan Wang and Lap Szeto and Chan, \{Wesley Ting Kwok\} and Ho-Lun Yeung and Ka-Leung Wong and Wing-Tak Wong",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

year = "2012",

month = jan,

doi = "10.1139/v11-132",

language = "English",

volume = "90",

pages = "100--107",

journal = "Canadian Journal of Chemistry",

issn = "0008-4042",

publisher = "National Research Council of Canada",

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TY - JOUR

T1 - Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

AU - Wang, Huaishan

AU - Szeto, Lap

AU - Chan, Wesley Ting Kwok

AU - Yeung, Ho-Lun

AU - Wong, Ka-Leung

AU - Wong, Wing-Tak

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2012/1

Y1 - 2012/1

N2 - Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.

AB - Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.

KW - 1,2-bis(4-pyridyl)hydrazine

KW - Coordination polymer

KW - Hydrogen bond

KW - Interpenetrating polymer

KW - Metal organic framework

KW - Microporous

UR - https://www.scopus.com/pages/publications/84855421542

UR - https://www.scopus.com/pages/publications/84855421542#tab=impact

U2 - 10.1139/v11-132

DO - 10.1139/v11-132

M3 - RGC 21 - Publication in refereed journal

SN - 0008-4042

VL - 90

SP - 100

EP - 107

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 1

ER -

Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Abstract

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Research Keywords

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